Thermochemical Oxygen Pumping with Perovskite Reticulated Porous Ceramics for Enhanced Reduction of Ceria in Thermochemical Fuel Production

Abstract

Within this work, reticulated monolithic foams and granules made from CaMnO3 − δ and strontium substituted variations are demonstrated to significantly improve the performance of a water splitting redox oxide when employed as a thermochemical oxygen pumping material. Two different process procedures are tested and foams made from Ca0.9Sr0.1MnO3 − δ with a strontium content of 10% outperform all other specimens in both process configurations. Additionally, the performance of Ca1 − xSrxMnO3 − δ with varying strontium content as a thermochemical oxygen pumping material is studied by means of a newly developed theoretical process model. While the model does not precisely predict the excellent experimental performance of strontium‐substitute compositions, it provides valuable insights into the impact of geometry and structure on the specimen's performance in thermochemical oxygen‐pumping processes. This work demonstrates the practical application of monolithic 3D structures made entirely from perovskite material in thermochemical oxygen pumping processes and provides a process model that can serve as basis for material screening and process optimization in future work.