Thermochemical parameters of dimethyl and di-iso-propyl dithiocarbamate complexes of palladium(II)

Knowledge of a Molecule: An Experimental and Theoretical Study of the Structure and Enthalpy of Formation of Tetrahydro-2H-1,3-oxazine-2-thione

“…After a long hiatus from a comprehensive study of such species early in the last century, the organic thermochemistry community has only in the last 10 years shown renewed interest in such compounds. − In contrast, the thermochemical study of ionic, metal, and more “inorganic” thiocarbamates and dithiocarbamates has been quite popular over the years. − …”

Thermal Analysis of Sulfur and Selenium Compounds with Multiple Applications, Including Anticancer Drugs

“…During the past decade the study of mixed sulfur donor ligand complexes with main group metals has made a progressive development due to the development of new analytical and structural techniques [60][61][62]. These complexes present potential applications in areas such as fast ion conductivity, photocatalysis and electro-optics, among others as well as several biochemical applications [63][64][65].…”

“…The thermal behaviour of Pd(II) complexes with some dithiocarbamate derivatives was studied in order to establish the coordination mode of the ligand, to test the thermal stability [11] or to understand the effect of the alkyl chain attached to the nitrogen atom over the thermochemical parameters of the complexes [74,75]. A series of Pd(II) complexes with tertbutylsarcosinedithiocarbamate [76], ethylsarcosinedithiocarbamate and 2-/3-picoline [77], dithiocarbamates and various amines [78] were developed as antitumor agents with low nephrotoxicity.…”

Thermochemical Parameters of Mercury(II) Chelates Involving Dimethyl and Di-isopropyl Dithiocarbamates

“…All solution calorimetric measurements were carried out in an LKB 8700-1 precision calorimeter, by the broken ampule method, as previously described. 8 Thermal decomposition of the complexes were determined by using a Shimadzu differential scanning DSC-50 calorimeter, with a heating rate of 10 K 3 min À1 and dry nitrogen as the purged gas. '…”

“…The stability of the complexes of palladium increases with the increase in size of the linear carbon chain and decreases with the alkyl substitution on it. 7,8 The synthesis of a new dithiocarbamate ligand and its complexes with copper(II), nickel(II) and palladium(II) as well as, their physicochemical characterization has been reported. Their thermal decomposition was continuous and the stabilities of the complexes were greater than that of the ligand.…”