Thermochemical study of cyanopyrazines: Experimental and theoretical approaches

Standard molar enthalpies of formation of 2-, 3- and 4-cyanobenzoic acids

“…However, the majority of the experimental works performed consider substituents such as methyl, amino, hydroxy, and halogens while the studies of the thermochemistry of compounds with other less common substituents such as the cyano group are rare [19,20]. In fact, the lack of experimental results involving compounds with the cyano group disallows us to be certain about the computational estimation of thermochemical parameters for other compounds containing the cyano group [21].…”