Thermochemistry of aksaite

A new magnesium borate MgO·B2O3·4H2O was synthesized by the method of phase transformation of double salt and characterized by XRD, IR spectra and TG. The structural formula of this compound was Mg·[B2O(OH)6]·H2O. The enthalpy of solution of MgO·B2O3·4H2O in HCl (1.0492 mol·L−1) was determined. With the incorporation of the standard molar enthalpies of formation of MgO (s), H3BO3(s), and H2O (1), the standard molar enthalpy of formation of ‐ (3135.31 ± 1.68) kJ·mol−1 of MgO·B2O3·4B2O was obtained. Thermodynamic properties of this compound were also calculated by group contribution method.

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Synthesis and Thermodynamic Properties of MgO·B₂O₃·4H₂O

Liu

Gao

et al. 2002

Chin. J. Chem.

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Experimental determination of solubilities of magnesium borates: Solubility constants of boracite [Mg3B7O13Cl(cr)] and aksaite [MgB6O7(OH)6·2H2O(cr)]

et al. 2018

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Thermochemistry of teepleite

Shu-guang

2001

Thermochimica Acta

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Thermochemistry of aksaite

Cited by 5 publications

References 8 publications

Synthesis and Thermodynamic Properties of MgO·B₂O₃·4H₂O

Synthesis and Thermodynamic Properties of MgO·B₂O₃·4H₂O

Experimental determination of solubilities of magnesium borates: Solubility constants of boracite [Mg3B7O13Cl(cr)] and aksaite [MgB6O7(OH)6·2H2O(cr)]

Thermochemistry of teepleite

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Thermochemistry of aksaite

Cited by 5 publications

References 8 publications

Synthesis and Thermodynamic Properties of MgO·B2O3·4H2O

Synthesis and Thermodynamic Properties of MgO·B2O3·4H2O

Experimental determination of solubilities of magnesium borates: Solubility constants of boracite [Mg3B7O13Cl(cr)] and aksaite [MgB6O7(OH)6·2H2O(cr)]

Thermochemistry of teepleite

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Product

Resources

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Synthesis and Thermodynamic Properties of MgO·B₂O₃·4H₂O

Synthesis and Thermodynamic Properties of MgO·B₂O₃·4H₂O