Thermochromic Luminescent Nest‐Like Silver Thiolate Cluster

Li, Bo; Huang, Ren‐Wu; Qin, Jian-Hua; Zang, Shuang‐Quan; Gao, Guanggang; Hou, Hongwei; Mak, Thomas C. W.

doi:10.1002/chem.201404049

Cited by 140 publications

(68 citation statements)

References 85 publications

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“…The tetranuclear cubane species [Cu 4 I 4 L 4 ]( L = phosphane, pyridine) represent the most studied family of temperature-responsive d 10 dual luminophores. The reported examples encompass Ag 31 /Ag 33 thiolatec lusters with ab athochromic shift of up to 2856 cm À1 in emissionu pon cooling from 298 to 77 K, [9] andacubane iodide complex, [Ag 4 I 4 (phosphane) 4 ], which demonstrates contrary temperature-dependent behavior for crystalline and powdered samples. [7] Furthermore, decoration of the {Cu 2 I 2 }c ore with two Cu 6 L 3 motifs (L = pyrazolyl pyridine derivative) produced ad ual-emissionc omplex with variable relative intensities of LE and HE bands over a wide range of temperatures.…”

Section: Introductionmentioning

confidence: 99%

Luminescence Thermochromism of Gold(I) Phosphane–Iodide Complexes: A Rule or an Exception?

Glebko

Dau

Melnikov

et al. 2018

Chemistry A European J

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A series of gold(I) iodide complexes 1-11 have been prepared from di-, tri-, and tetraphosphane ligands. Crystallographic studies reveal that the di- (1-7) and tetrametallic (11) compounds feature linearly coordinated gold(I) ions with short aurophilic contacts. Their luminescence behavior is determined by the combined influence of the phosphane properties, metal-metal interaction, and intermolecular lattice-defined interactions. The proposed variable contribution of (X+M)-centered (X=halogen; M=metal) and XLCT (halogen to ligand charge transfer) electronic transitions into the lowest lying excited state, which is influenced by supramolecular packing, is presumably responsible for the alteration of room-temperature emission color from green (λ=545 nm, for 11) to near-IR (λ=698 nm, for 2). Dinuclear compounds 6 and 7 exhibit distinct luminescence thermochromism with a blueshift up to 5750 cm upon cooling. Such dramatic change of emission energy is assigned to the presence of two coupled triplet excited states of ππ* and (X+M)C/ XLCT nature, the presence of which depends on both molecular structure and the crystal lattice arrangement.

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Section: Introductionmentioning

confidence: 99%

Luminescence Thermochromism of Gold(I) Phosphane–Iodide Complexes: A Rule or an Exception?

Glebko

Dau

Melnikov

et al. 2018

Chemistry A European J

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“…[10] Recent studies indicatedt hat the small linking anion/ligand matched well with large clusters in the assembly of 3D MOFs such as Gd 36 and Dy 36 based 3D MOFs linked by nicotinic acid [11] and the Ag 31 clusterb ased 2D layer linked by NO 3 À anions. [12] Overall, it is still of great interestt ou nmask the interesting structures and special properties when nanosized silver clusters are effectively integrated into crystalline MOFs.…”

Section: Introductionmentioning

confidence: 99%

Beyond Clusters: Supramolecular Networks Self‐Assembled from Nanosized Silver Clusters and Inorganic Anions

Wang

Liu

et al. 2016

Chemistry A European J

121

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Assembly of small clusters into rigid bodies with precise shape and symmetry has been witnessed by the significant advances in cluster-based metal-organic frameworks (MOFs), however, nanosized silver cluster based MOFs remain largely unexplored. Herein, two anion-templated silver clusters, CO3 @Ag20 and SO4 @Ag22 , were ingeniously incorporated into a 2D sql lattice (1, [CO3 @Ag20 (iPrS)10 (NO3 )8 (DMF)2 ]n ) and an unprecedented 3D two-fold interpenetrated dia network (2, [SO4 @Ag22 (iPrS)12 (NO3 )6 ⋅2 NO3 ]n ), respectively, under mild solvothermal conditions. Their atomically precise structures were confirmed by single-crystal X-ray diffraction analysis and further consolidated by IR spectroscopy, thermogravimetric analysis (TGA), and elemental analysis. Each drum-like CO3 @Ag20 cluster is extended by twelve NO3 (-) ions to form the 2D sql lattice of 1, whereas each ball-shaped SO4 @Ag22 cluster with a twisted truncated tetrahedral geometry is pillared by four [Ag6 (NO3 )3 ] triangular prisms to form the 3D interpenetrated dia network of 2. Notably, 2 is the first interpenetrated 3D MOF constructed from silver clusters. These results demonstrate the dual role of the anions, which not only internally act as anion templates to induce the formation of silver thiolate clusters but also externally extend the cluster units into the rigid networks. The photoluminescent and electrochemical properties of 2 are discussed in detail.

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“…This phenomenon is probably from the thermally active phononassisted tunneling between the excited states of low-energy site and the excited states of high-energy site. 83,84 ■ CONCLUSIONS In summary, a series of novel capsule-based CPs have been hydrothermally synthesized by using the new bowl-like TTR4A ligand and various dicarboxylates. These CPs show the charming 2D and 3D network structures.…”

Section: Crystal Growth and Designmentioning

confidence: 99%

A Family of Capsule-Based Coordination Polymers Constructed from a New Tetrakis(1,2,4-triazol-ylmethyl)resorcin[4]arene Cavitand and Varied Dicarboxylates for Selective Metal-Ion Exchange and Luminescent Properties

Yang

Liu

et al. 2015

Crystal Growth & Design

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A series of novel capsule-based coordination polymers (CPs), namely, [Cd(TTR4A)(L1)]·2.5H 2 O (1), [Cd(TTR4A)(L2)]·2DMF·2H 2 O (2), [Cd(TTR4A)(L3)]·2DMF·1.5H 2 O (3), [Cd(TTR4A)(L4)]·1.5H 2 O (4), and [Zn(TTR4A)(L1)]·DMF·H 2 O (5), have been synthesized via the reaction of a bowl-like tetrakis(1,2,4-triazol-ylmethylresorcin[4]arene (TTR4A) ligand with d 10 metal salts in the presence of varied dicarboxylates (H 2 L1 = fumaric acid, H 2 L2 = 1,3-benzenedicarboxylic acid, H 2 L3 = 5-hydroxy-1,3-benzenedicarboxylic acid, H 2 L4 = biphenylethene-4,4′-dicarboxylic acid, and DMF = N,N-dimethylformamide). CPs 1−3 show rare two-dimensional (2D) capsulebased network structures. In 1−3, two TTR4A bowls share two Cd(II) cations to give a capsule, which is further extended by the dicarboxylates into 2D networks. CP 4 features a fascinating three-dimensional 3-connected framework structure constructed from bowl-like [Cd 2 TTR4A] units and L4 anions. In 5, each TTR4A coordinates with two Zn(II) cations by using two 1,2,4-triazole groups to generate a capsule, which is further connected by L1 ligands to afford a 2D network structure. Significantly, solid-state emissions and temperature variable luminescence were studied for 1−4. In particular, the remarkable metal-ion exchange property of CP 1 was investigated.

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Thermochromic Luminescent Nest‐Like Silver Thiolate Cluster

Cited by 140 publications

References 85 publications

Luminescence Thermochromism of Gold(I) Phosphane–Iodide Complexes: A Rule or an Exception?

Luminescence Thermochromism of Gold(I) Phosphane–Iodide Complexes: A Rule or an Exception?

Beyond Clusters: Supramolecular Networks Self‐Assembled from Nanosized Silver Clusters and Inorganic Anions

A Family of Capsule-Based Coordination Polymers Constructed from a New Tetrakis(1,2,4-triazol-ylmethyl)resorcin[4]arene Cavitand and Varied Dicarboxylates for Selective Metal-Ion Exchange and Luminescent Properties

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