Thermodynamic Analyses on Nanoarchitectonics of Perovskite from Lead Iodide: Arrhenius Activation Energy

Borrero, Nelson Fabián Villegas; Filho, José Maria Clemente da Silva; Coutinho, Natália F.; Freitas, Jilian Nei de; Marques, F. C.

doi:10.1007/s10904-021-02169-w

Cited by 6 publications

(9 citation statements)

References 40 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…erefore, when the pH value of rainfall is less than 5.6, it can be defined as acid rain [19]. Acid rain has become one of the serious environmental problems in China.…”

Section: Influence Of Acid Rain On Durability Of the Cfrp Boltmentioning

confidence: 99%

Durability Test and Mechanical Properties of CFRP Bolt under Accelerated Corrosion Conditions

Guo

2022

Journal of Chemistry

View full text Add to dashboard Cite

In order to study the influence of acid corrosion on the quality, elastic modulus, tensile strength, elongation, and other properties of epoxy mortar test block and CFRP bolt, the durability test and mechanical properties test of CFRP bolt under accelerated corrosion conditions were proposed. An epoxy mortar test block was soaked in acidic solution for 90 d, and the quality, elastic modulus, tensile strength, elongation, and other properties of CFRP bolt were analyzed. Through the analysis of test data, the load-slip relationship curve of bolt was obtained and the Arrhenius equation was used. The relationship curve between tensile strength retention and logarithm of time in test environment was obtained, and the concept of conversion factor TSF was introduced to predict the strength retention of anchor corroded by acid rain for 20 years in service. The experimental results show that the maximum loss rates of mass, elastic modulus, and compressive strength of epoxy mortar test block are 1.98%, 2.81%, and 11.25%, respectively, during 90 d immersion in acidic solution. The maximum loss rates of mass, elastic modulus, tensile strength, and elongation of CFRP bolt are 0.65%, 3.29%, 6.51%, and 5.06%, respectively. Based on the analysis of the test data, the load-slip curve of the bolt is obtained, which indicates that acid corrosion reduces the bond performance of CFRP bolt. The bond-slip curve of bolt after 90 d acid corrosion was obtained by further analysis of experimental data. Conclusion. The experiment has certain engineering application values.

show abstract

“…erefore, when the pH value of rainfall is less than 5.6, it can be defined as acid rain [19]. Acid rain has become one of the serious environmental problems in China.…”

Section: Influence Of Acid Rain On Durability Of the Cfrp Boltmentioning

confidence: 99%

Durability Test and Mechanical Properties of CFRP Bolt under Accelerated Corrosion Conditions

Guo

2022

Journal of Chemistry

View full text Add to dashboard Cite

show abstract

“…244 Alternatively, a two-step process can also be adopted, where the first layer of PbI 2 is deposited by evaporation and then converted to perovskite by contact with MAI vapor or solution. 94 The most common approach, however, is multisource co-evaporation, in which the precursors are loaded into separate crucibles and evaporated all together to form the perovskite layer. Even though thermal annealing is still used in many studies to improve the quality of evaporated films, 245,246 it is possible to make crystalline perovskite layers without thermal annealing by using thermal evaporation.…”

Section: Perovskite Film Formation From Solid Precursorsmentioning

confidence: 99%

In Situ and Operando Characterizations of Metal Halide Perovskite and Solar Cells: Insights from Lab-Sized Devices to Upscaling Processes

et al. 2023

View full text Add to dashboard Cite

The performance and stability of metal halide perovskite solar cells strongly depend on precursor materials and deposition methods adopted during the perovskite layer preparation. There are often a number of different formation pathways available when preparing perovskite films. Since the precise pathway and intermediary mechanisms affect the resulting properties of the cells, in situ studies have been conducted to unravel the mechanisms involved in the formation and evolution of perovskite phases. These studies contributed to the development of procedures to improve the structural, morphological, and optoelectronic properties of the films and to move beyond spin-coating, with the use of scalable techniques. To explore the performance and degradation of devices, operando studies have been conducted on solar cells subjected to normal operating conditions, or stressed with humidity, high temperatures, and light radiation. This review presents an update of studies conducted in situ using a wide range of structural, imaging, and spectroscopic techniques, involving the formation/ degradation of halide perovskites. Operando studies are also addressed, emphasizing the latest degradation results for perovskite solar cells. These works demonstrate the importance of in situ and operando studies to achieve the level of stability required for scale-up and consequent commercial deployment of these cells.

show abstract

“…Bulk-perovskite thin films can be prepared through a precursor solution containing the lead and A-site cation salts in the desired solvent, and deposited by a large variety of techniques such as spin-coating, 98,107 spray, 108 inkjet printing, 109,110 blade-coating, 111,112 thermal evaporation, 113,114 rfsputtering, [114][115][116][117][118] slot-die coating, 119 chemical vapor deposition, 120 and atomic layer deposition. 121 2D layered perovskite solar cells have been mainly deposited by solution processes, and also involve the preparation of a precursor solution.…”

Section: Synthesis Of Perovskite Nanocrystalsmentioning

confidence: 99%

Tiny spots to light the future: advances in synthesis, properties, and application of perovskite nanocrystals in solar cells

et al. 2023

View full text Add to dashboard Cite

show abstract

Thermodynamic Analyses on Nanoarchitectonics of Perovskite from Lead Iodide: Arrhenius Activation Energy

Cited by 6 publications

References 40 publications

Durability Test and Mechanical Properties of CFRP Bolt under Accelerated Corrosion Conditions

Durability Test and Mechanical Properties of CFRP Bolt under Accelerated Corrosion Conditions

In Situ and Operando Characterizations of Metal Halide Perovskite and Solar Cells: Insights from Lab-Sized Devices to Upscaling Processes

Tiny spots to light the future: advances in synthesis, properties, and application of perovskite nanocrystals in solar cells

Contact Info

Product

Resources

About