Thermodynamic analysis and process simulation for the H2 production by dry reforming of ethanol with CaCO3

López-Ortíz, Alejandro; Sámano, R.B. Pallares; Zaragoza, M.J. Meléndez; Collins-Martı́nez, V.

doi:10.1016/j.ijhydene.2015.07.115

Cited by 23 publications

(5 citation statements)

References 39 publications

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“…The simulation of dry reforming of ethanol by thermodynamic analysis has been studied to determine optimum conditions for H 2 production [16][17][18]. Figure 4 showed the variation of gas composition with temperature.…”

Section: Dry Reforming Of Ethanolmentioning

confidence: 99%

Dry Reforming of Ethanol and Glycerol: Mini-Review

Odriozola

Reina

2019

Catalysts

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Dry reforming of ethanol and glycerol using CO2 are promising technologies for H2 production while mitigating CO2 emission. Current studies mainly focused on steam reforming technology, while dry reforming has been typically less studied. Nevertheless, the urgent problem of CO2 emissions directly linked to global warming has sparked a renewed interest on the catalysis community to pursue dry reforming routes. Indeed, dry reforming represents a straightforward route to utilize CO2 while producing added value products such as syngas or hydrogen. In the absence of catalysts, the direct decomposition for H2 production is less efficient. In this mini-review, ethanol and glycerol dry reforming processes have been discussed including their mechanistic aspects and strategies for catalysts successful design. The effect of support and promoters is addressed for better elucidating the catalytic mechanism of dry reforming of ethanol and glycerol. Activity and stability of state-of-the-art catalysts are comprehensively discussed in this review along with challenges and future opportunities to further develop the dry reforming routes as viable CO2 utilization alternatives.

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Section: Dry Reforming Of Ethanolmentioning

confidence: 99%

Dry Reforming of Ethanol and Glycerol: Mini-Review

Odriozola

Reina

2019

Catalysts

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show abstract

“…Several studies [8,[58][59][60] have evaluated the thermodynamic aspects of the reactions related to ethanol steam reforming. For example, the water-gas shift reaction, with the conversion of carbon monoxide and water into carbon dioxide and molecular hydrogen, is an exothermic reaction that is favored at low temperatures.…”

Section: Catalytic Activitymentioning

confidence: 99%

Sol-gel synthesis of nanocrystalline MgO and its application as support in Ni/MgO catalysts for ethanol steam reforming

Possato

Gonçalves

Santos

et al. 2021

Applied Surface Science

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“…Formation of carbon and consequently catalyst deactivation during the reforming process is an essential subject which can impact the catalyst performance. Both equilibrium and experimental analyses were performed by [40], [46], [53], [54], [55] on the reforming of pure ethanol and butanol in the wide range of temperatures and steam to carbon molar ratios. The results revealed that carbon formation can be insignificant under presented steam and O2 additions.…”

Section: Experimental Analysis Of H2 and H2o Exhaust Gas Fuel Reforma...mentioning

confidence: 99%

Synergies in renewable fuels and exhaust heat thermochemical recovery in low carbon vehicles

et al. 2021

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Thermodynamic analysis and process simulation for the H2 production by dry reforming of ethanol with CaCO3

Cited by 23 publications

References 39 publications

Dry Reforming of Ethanol and Glycerol: Mini-Review

Dry Reforming of Ethanol and Glycerol: Mini-Review

Sol-gel synthesis of nanocrystalline MgO and its application as support in Ni/MgO catalysts for ethanol steam reforming

Synergies in renewable fuels and exhaust heat thermochemical recovery in low carbon vehicles

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