Thermodynamic and Dynamic Properties of Polymers in Liquid and Supercritical Solvents

Melnichenko, Yuri B.; Wignall, G. D.; Brown, Wyn; Kiran, Erdoǧan; Cochran, H. D.; Salaniwal, Sumeet; Heath, K.D.; VanHook, W. A.; Stamm, Manfred

doi:10.1007/0-306-47110-8_2

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The Nascent Morphology Of Polyolefin Particles and Polymers1

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2009

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“…Let us consider now the solvent effect on the growing chains. It should be noted that the quality of the solvent (namely poor, theta and good solvents) is directly related to the ability of the solvent to mediate the attractive intra‐chain forces responsible for the polymer demixing 58. In other words, just as in the case of the influence of the temperature, the solvent is able to influence how many segments of the growing chain are found in the ‘liquid’ state.…”

Section: The Nascent Morphology Of Polyolefin Particles and Polymersmentioning

confidence: 99%

Particle Growth During the Polymerisation of Olefins on Supported Catalysts, 1 – Nascent Polymer Structures

McKenna

Martino

Weickert

et al. 2009

Macro Reaction Engineering

120

127

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It is shown that the relationship between the catalyst/polymer structure, process conditions and final product properties needs to be addressed in more detail. From an industrial point of view, the interest starts from the need to control the growth of the catalyst/polymer particle during the polymerisation process. This first part of a two-part review discusses the different factors that can influence the physical properties of the nascent polymer, and how these can impact the evolution of particle morphology. 40

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Section: The Nascent Morphology Of Polyolefin Particles and Polymersmentioning

confidence: 99%

Particle Growth During the Polymerisation of Olefins on Supported Catalysts, 1 – Nascent Polymer Structures

McKenna

Martino

Weickert

et al. 2009

Macro Reaction Engineering

120

127

View full text Add to dashboard Cite

show abstract

Thermodynamic and Dynamic Properties of Polymers in Liquid and Supercritical Solvents

Cited by 1 publication

References 23 publications

Particle Growth During the Polymerisation of Olefins on Supported Catalysts, 1 – Nascent Polymer Structures

Particle Growth During the Polymerisation of Olefins on Supported Catalysts, 1 – Nascent Polymer Structures

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