2004
DOI: 10.1016/j.jct.2004.04.011
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Thermodynamic evaluation and optimization of the (NaCl+KCl+AlCl3) system

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Cited by 56 publications
(34 citation statements)
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“…Throughout this manuscript, samples A and A1 are crystals grown with the first method and sample B is a crystal grown with the second method. The flux's melting point determined the temperature range for the growth [5,6]. The lower temperature of the second method allows us to grow the crystals in the desired phase avoiding high temperature structural phase transitions and decompositions [1].…”
Section: Crystal Characterizationmentioning
confidence: 99%
“…Throughout this manuscript, samples A and A1 are crystals grown with the first method and sample B is a crystal grown with the second method. The flux's melting point determined the temperature range for the growth [5,6]. The lower temperature of the second method allows us to grow the crystals in the desired phase avoiding high temperature structural phase transitions and decompositions [1].…”
Section: Crystal Characterizationmentioning
confidence: 99%
“…The liquid solution is modelled using the Modified Quasichemical Model [2,3] which takes into account short-range ordering between nearest-neighbours on a lattice or sublattice. This model has been used successfully to model systems such as (LiCl + NaCl + KCl + RbCl + CsCl + MgCl 2 + CaCl 2 ) [4], (NaCl + KCl + MgCl 2 + CaCl 2 + MnCl 2 + FeCl 2 + CoCl 2 + NiCl 2 ) [5,6], (NaCl + KCl + AlCl 3 ) [7], and (LiF + NaF + KF + MgF 2 + CaF 2 ) [1].…”
Section: Introductionmentioning
confidence: 99%
“…Highpurity alkali metal salts (99.99%) and anhydrous AlCl 3 (99.99%) procured from Alfa Aesar were used to synthesize ternary catholytes, following a method reported in the literature [19]. Alkali metal salts (a mixture of NaCl and another salt) and AlCl 3 were mixed in the molar ratio of 1.15 to 1 and homogenized at 320 C in a three neck flask which was purged with ultra-high purity (UHP) argon.…”
Section: Materials and Synthesismentioning
confidence: 99%