Thermodynamic investigation of room temperature ionic liquid: The heat capacity and standard enthalpy of formation of EMIES

Excess enthalpy, density, and heat capacity for binary systems of alkylimidazolium-based ionic liquids+water

“…Their capabilities as environmental-friendly solvents have been extensively demonstrated for most of the main chemical processes [1][2][3][4][5][6][7][8][9][10]. As for thermodynamics, there are several publications devoted to experimental and theoretical study of pure compounds and their mixtures with common organic solvents [11][12][13][14][15][16][17][18][19][20][21][22][23][24][25][26][27][28][29][30]. In fact, there is an important body of knowledge about the thermophysical properties for most of RTILs commercially available.…”

Volumetric properties, viscosity and refractive index of the protic ionic liquid, pyrrolidinium octanoate, in molecular solvents

“…Due to unique chemical and physical propertiesincluding thermal stability, a high solubility power, and extremely low vapor pressure-ILs can serve as new solvents for catalysis, synthesis and extraction as an alternative to volatile organic compounds, which are traditionally used in industrial processes [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15]. ILs formed by the transfer of a protons between a Brønsted acid and a Brønsted base, form a protic subgroup in the class of ambient temperature fluid systems now referred as ''Protic Ionic Liquids (PILs)".…”

Excess molar properties for binary systems of alkylimidazolium-based ionic liquids+nitromethane. Experimental results and ERAS-model calculations

“…Study of room temperature ionic liquids (RTILs) as solvents has received an increasing attention in the last years from fundamental and applied points of view [1][2][3][4][5][6][7][8][9][10][11][12][13][14][15]. As for thermodynamics of RTILs in solution with other compounds, there are many experimental and theoretical studies which deal on the behavior of thermodynamic properties of mixtures RTIL + common organic solvent [16][17][18][19][20][21][22][23][24][25][26][27][28][29][30][31][32][33]; however, due to the enormous number of possible binary systems, a lot of work remains to be done.…”