Thermodynamic investigation of the solid and liquid AuSb alloys

Anrés, P.; Bros, H.; Castanet, R.

doi:10.1016/0966-9795(94)90014-0

Cited by 8 publications

(18 citation statements)

References 11 publications

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“…As can be see in Fig. 1, good agreement was obtained between calculated and experimental data of the enthalpy of mixing newly reported by Anres et al 4 and Hayer and Castanet. 5 The assessed enthalpies of mixing of liquid Au-Sb alloys by Chevalier 3 are also demonstrated in Fig.…”

Section: The Au-sb Systemsupporting

confidence: 89%

“…1. It is clear that the values assessed by Chevalier 3 deviate significantly from both the calculated values in this work and those experimental data measured by Anres et al 4 and Hayer and Castanet, 5 especially in the Au-rich part. It should be pointed out that the enthalpies of mixing used in previous optimization by Chevalier 3 were taken from Kameda et al 10 and Hino et al, 11 which were deduced from activities of Sb in liquid alloys.…”

Section: The Au-sb Systemcontrasting

confidence: 71%

“…The thermodynamic assessment of the Au-Sb binary system was previously performed by Chevalier, 3 and phase relationships of this system were well reproduced. However, the calculated values of the mixing enthalpy of liquid AuSb alloys deviate significantly from new experimental data directly measured by means of calorimetry by Anres et al 4 and Hayer and Castanet. 5 Considering the accuracy of the enthalpy of mixing obtained through different methods, the newly reported data are obviously more reliable (the detailed analysis will be given later).…”

Section: Introductioncontrasting

confidence: 53%

“…11 Recently, by using calorimetry, enthalpies of mixing of liquid Au-Sb alloys were measured at different temperatures, 4,5 which indicate its dependence on temperature.…”

Section: Thermodynamic Propertiesmentioning

confidence: 99%

“…5 Values from both resources 5,16 show good agreement. By calorimetry, heat content of the alloy AuSb 2 and the alloy of Aurich eutectic composition at different temperatures were measured from 298 K to 963 K by Anres et al 4 and from 298 K to 846 K by Yassin and Castanet,17 respectively. All these data consist of the basis of the present optimization of the Au-Sb binary system.…”

Section: Thermodynamic Propertiesmentioning

confidence: 99%

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Thermodynamic modeling of the Au-In-Sb ternary system

Liu

Wang

et al. 2003

Journal of Elec Materi

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The phase diagram of the Au-In-Sb ternary system is of importance in predicting the interface reaction between In-based solders and the Au substrate. Using the calculated phase diagram method and based on experimental data of thermodynamic properties and phase boundaries, the Au-Sb binary system was assessed, and the In-Sb binary system was revised. On the basis of the constituent binary systems, Au-Sb, In-Sb, and Au-In, the Au-In-Sb ternary system was modeled. Several isothermal and vertical sections were calculated, among which the one at 500 K reproduces the experimental diagram well.

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Section: The Au-sb Systemsupporting

confidence: 89%

Section: The Au-sb Systemcontrasting

confidence: 71%

Section: Introductioncontrasting

confidence: 53%

“…11 Recently, by using calorimetry, enthalpies of mixing of liquid Au-Sb alloys were measured at different temperatures, 4,5 which indicate its dependence on temperature.…”

Section: Thermodynamic Propertiesmentioning

confidence: 99%

Section: Thermodynamic Propertiesmentioning

confidence: 99%

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Thermodynamic modeling of the Au-In-Sb ternary system

Liu

Wang

et al. 2003

Journal of Elec Materi

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Ternary Au-Ga-Sb system: calculation of thermodynamic properties using general solution model

et al. 2015

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Thermodynamic modeling of the Au–Sb–Si ternary system

Wang

Liu

et al. 2011

Journal of Alloys and Compounds

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a b s t r a c tThermodynamic optimization of the Au-Sb binary system was updated as well as the Si-Sb binary system was assessed thermodynamically using the CALPHAD method based on the critical review of the available experimental information from the published literature. The solution phases including liquid, fcc A1(Au), diamond A4(Si) and rhombohedral A7(Sb), are modeled as substitutional solutions and their excess Gibbs energies are expressed by a Redlich-Kister polynomial. The solubility of Si in the intermetallic compound AuSb 2 is not taken into account because of the lack of experimental information. Combined with previous assessment of the Au-Si binary system, thermodynamic modeling of the Au-Sb-Si ternary system was performed to reproduce well the measured phase equilibria. The liquidus projection and several vertical sections of this ternary system were calculated, which are in reasonable agreement with the reported experimental data.

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Thermodynamic investigation of the solid and liquid AuSb alloys

Cited by 8 publications

References 11 publications

Thermodynamic modeling of the Au-In-Sb ternary system

Thermodynamic modeling of the Au-In-Sb ternary system

Ternary Au-Ga-Sb system: calculation of thermodynamic properties using general solution model

Thermodynamic modeling of the Au–Sb–Si ternary system

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