Sorption-assisted atmospheric water
harvesting (SAWH)
is a promising
strategy to mitigate the worldwide upsurge in freshwater demand. To
empower the sustainable approach, suitable sorbent materials such
as hydrogels, metal–organic frameworks (MOFs) and their composite
structures have gained significant attention at the advent of their
unique surface features like tunable porosity, high surface area,
stimuli-responsiveness, and absorption desorption channels through
functional sites. Delving into challenges associated with SAWH, we
have presented a composite sorbent material consisting of alanine
amino acid-based hydrogel and Al MOF. Stressing upon the fine-tuning
of two individual sorbents, we designed several hydrogel-MOF composites
and optimized the concentration of Al-MOF with 7.5 wt % of 0.5AHN
with the best water uptake, moisture sorption, and desalination efficiency.
The synergistic combination of inherently zwitterionic amino acid-based
hydrogels with MOF opened up extended water uptake channels for the
overall composite. As a result of such irreversible interaction, 0.5AHN_AlM(7.5) exhibited the highest sorption capacity of 2.21 g g–1 at 90% RH, whereas 0.26 and 0.47 g g–1 moisture uptake was measured at humidity levels of 40% RH and 60%
RH, respectively. Moreover, with an evaporation rate of 0.79 kg m–2 h–1, 3.4 g of saline water was
converted into freshwater within 3.5 h of solar irradiation to demonstrate
its desalination efficiency. This study aims to establish a strategic
method for creating environmentally friendly and effective composite
materials that can be used to enhance and automate solar-powered SAWH.