Thermodynamic modeling of redox equilibria in sodium silicate glasses with low iron content

Dunaeva, E. S.; Brunet, E.; Müller, Sven; Uspenskaya, I. A.

doi:10.1134/s0036023612100051

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Causes and Effects Of Fe 3+ /Sfe In Glass1

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“…Concerning the temperature, ancient furnaces were capable of reaching 1100-1200 C. 28,30,[38][39][40] For a given soda-lime-silicate system, increasing the melting temperature promotes the formation of Fe 2+ . [41][42][43] When the melting temperature is low and the amount of alkali is high, ancient glass should be oxidised. On the other hand, a typical Roman glass is partially reduced having a typical blue-green hue.…”

Section: Causes and Effects Of Fe 3+ /Sfe In Glassmentioning

confidence: 99%