Thermodynamic properties of microporous materials for two copper borates, MCuB7O12·H2O (M=Na,K)

Zhang, Hui-Hui; Kong, Na; Wang, Jie; Liu, Zhihong

doi:10.1016/j.jct.2015.04.038

Cited by 7 publications

(2 citation statements)

References 15 publications

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“…Copper borates are mostly utilized in linear and non-linear optical devices, hydrogen generation systems, and photocatalytic reactions. Also, this type of borate has applications in fire retardants, wood preservation, the design of ion exchange materials, and lubricant additives (6)(7)(8)(9). These characteristics make their synthesis important.…”

Section: Introductionmentioning

confidence: 99%

Sonochemical Synthesis of Copper Borates: Effect of Reaction Conditions on the Characteristic Properties

Şenberber Dumanlı,

Karaağaç,

Kıpçak

et al. 2024

Journal of the Turkish Chemical Society Section A: Chemistry

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The effect of ultrasonic treatment on liquid-state production and the characteristic features of synthesized powder were studied in liquid-state conditions. In sonochemical synthesis, the operation parameters of mole ratio, reaction temperature, and time were optimized. The synthesis was achieved in moderate conditions such as mole ratio of copper: sodium: boron (Cu: Na: B) 1:2:1, 70°C and 2.5 minutes. The prepared samples were identified as copper borate (Cu(BO2)2) with the powder diffraction file number "00-001-0472". The reaction yields were also increased from 50% to 71.5% with the modification of the experimental procedure. The specific FT-IR peaks were observed at 1090, 985, 872, 781 and 731 cm-1 band values. In the morphological analyses, the agglomerations of multi-angular particles were seen. The results showed the affirmative effects of the possible use of the ultrasonic treatment on both the practical synthesis and the increase of characteristics.

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Section: Introductionmentioning

confidence: 99%

Sonochemical Synthesis of Copper Borates: Effect of Reaction Conditions on the Characteristic Properties

Şenberber Dumanlı,

Karaağaç,

Kıpçak

et al. 2024

Journal of the Turkish Chemical Society Section A: Chemistry

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“…Navrotsky group has done much work on the thermochemistry of microporous compounds such as zeolites, pure silica, gallosilicate, and aluminophosphates by using high-temperature calorimetry [4,5]. Our group has reported the thermodynamic properties of several boron-containing microporous materials [6][7][8][9][10]. As part of the continuing study of this work, this paper reports the determination of standard molar enthalpies of formation of two transition metal borates microporous materials of Na 2 Co 2 B 12 O 21 and Na 2 Cu 2 B 12 O 21 by using a heat conduction microcalorimeter.…”

Section: Introductionmentioning

confidence: 99%

Thermodynamic properties of two microporous materials for Na 2 [M 2 B 12 O 21 ] (M = Co 2+ , Cu 2+ )

Geng

Wang

Liu

2016

The Journal of Chemical Thermodynamics

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Thermochemical properties of two mixed alkali-alkaline earth metal borates with NLO properties for NaCaBO 3 and Li 4 CaB 2 O 6

Zhao

Liu

2018

The Journal of Chemical Thermodynamics

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Thermodynamic properties of microporous materials for two copper borates, MCuB7O12·H2O (M=Na,K)

Cited by 7 publications

References 15 publications

Sonochemical Synthesis of Copper Borates: Effect of Reaction Conditions on the Characteristic Properties

Sonochemical Synthesis of Copper Borates: Effect of Reaction Conditions on the Characteristic Properties

Thermodynamic properties of two microporous materials for Na 2 [M 2 B 12 O 21 ] (M = Co 2+ , Cu 2+ )

Thermochemical properties of two mixed alkali-alkaline earth metal borates with NLO properties for NaCaBO 3 and Li 4 CaB 2 O 6

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