Thermodynamic properties of the pseudo-binary CsCl–LnCl3   (Ln=Ce,Pr,Nd) systems

Prediction of the thermodynamic data of the pseudobinary alkali halide–lanthanide halide condensed systems

“…The entropy of mixing of the liquid CsCl-PrCl 3 system is close to zero. This is consistent with the results obtained for similar systems [4]. Taking into account the above considerations the authors invite question: Do results obtained for CsCl-PmCl 3 system are connected with instability of Pm?…”

Crystal structure, electronic structure, temperature-dependent optical and scintillation properties of CsCe2Br7

“…[9][10][11] The CsCe 2 Cl 7 with a density of 3.6 g cm À3 can reach a gamma-ray excited light yield of 26 000 photons per MeV, but a 50% higher light yield is achieved in CsCe 2 Br 7 with a higher density of 4.0 g cm À3 . The phase diagrams of CsCe 2 Cl 7 12 and CsCe 2 Br 7 13,14 indicate that they both melt congruently. Recently, the crystal structure refinement revealed that CsCe 2 Cl 7 crystallizes in the monoclinic space group P112 1 /b.…”

The NaDyBr4 complex; its molecular structure and thermodynamic properties

“…The growing interest in the NaBr-DyBr 3 system is illustrated by recent studies of their Z. Varga · M. Hargittai ( ) Structural Chemistry Research Group of the Hungarian Academy of Sciences at Eötvös University, P.O.Box 32, H-1518, Budapest, Hungary e-mail: hargitta@chem.elte.hu mass spectra [5] and phase diagrams [6]. Mass spectrometry has proved to be the major experimental tool to study these systems [4,5,[7][8][9][10][11][12][13][14][15][16][17], yielding information about the composition and thermochemical properties of the systems found in the vapor. Modeling the processes in the high-temperature lamp facilitates improving lamp designs.…”