Thermodynamic properties of the silver ion in alcohol + water solvent mixtures from electromotive force measurements and thermodynamic solubility product constants of AgX (X = Cl, Br, I or CNS) at different temperatures

Enthalpies and Entropies of Transfer of Electrolytes and Ions from Water to Mixed Aqueous Organic Solvents

“…Data reported 80 for a number of salts at the single composition x MeOH = 0.568 are not listed in Table but are cited in its footnotes and in the text below. The potentiometric measurements reported by Dash and co-workers − for a number of silver and mercury salts at low cosolvent concentrations contained too little useful information to justify their inclusion, as also did the paper by Krasnoperova 3 Δ t H °(MX, w → w + MeOH)/kJ mol -1 , 298.15 K, as a Function of 100 x MeOH MXΔ sln H °5102030405060708090100ref HCl −74.81 1.26 2.11 2.77 2.43 1.47 0.18 −1.25 −2.72 −4.21 −5.79 −7.63 5 HCl −75.7 [2.4] [3.3] [2.7] [0.6] [−1.8] [−4.1] [−6.3] [−8.3] [−9.3] [−7.1] [−2.1] 74 HCl 1.35 2.32 (3.33) 3.21 (2.26) 0.75 −1.07 (−2.99) −4.80 −6.37 −7.56 54 HCl 1.3 2.2 3.1 2.8 1.9 0.5 − 1.1 − 2.8 − 4.5 − 6.1 − 7.6 HBr 1.15 1.91 (2.68) 2.32 (0.89) −1.40 −4.26 (−7.28) −9.95 −11.64 −11.63 54 HI 1.07 1.60 (2.18) 1.77 (0.17) −2.58 −6.21 (−10.28) −13.86 −16.17 −15.93 54 HI 0.95 0.83 −2.65 −8.33 −14.72 −20.59 −24.94 −27.04 −26.40 −22.06 −16.11 75 H 2 CrO 4 3.36 5.71 ...…”