Thermodynamic re-optimization of the ACl -MgCl2 (A=Na, K, Rb, Cs and Ca, x=1 or 2) systems

Song, Jinliang; Liu, Wenguan; Hu, Biao

doi:10.1016/j.calphad.2022.102476

Search citation statements

Order By: Relevance

Paper Sections

Select...

Results1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article2

Relationship

Self Cite0

Independent2

Authors

Journals

Cited by 2 publications

(1 citation statement)

References 32 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…DSC of Cs 2 MgCl 4 and Cs 3 MgCl 5 was measured to confirm the reported congruent melting of these compounds, 46–49 which is favorable for melt growth techniques such as the Bridgman method. A single endothermic and single exothermic peak are observed in the DSC curves of each (Fig.…”

Section: Resultsmentioning

confidence: 74%

New ultrafast scintillators with core valence luminescence: Cs₂MgCl₄ and Cs₃MgCl₅

Rutstrom,

Stand,

Windsor

et al. 2024

J. Mater. Chem. C

View full text Add to dashboard Cite

show abstract

Section: Resultsmentioning

confidence: 74%

New ultrafast scintillators with core valence luminescence: Cs₂MgCl₄ and Cs₃MgCl₅

Rutstrom,

Stand,

Windsor

et al. 2024

J. Mater. Chem. C

View full text Add to dashboard Cite

show abstract

Probing the Ionic Coordination in MgCl₂–KCl Mixed Salts by Quadrupolar ³⁵Cl NMR

Sun,

Wu,

Yingsu

et al. 2024

J. Phys. Chem. C

View full text Add to dashboard Cite

MgCl 2 −KCl mixed salts have been identified as promising thermal energy storage (TES) media and heat transfer fluids (HTF) for concentrated solar power (CSP) systems and other energy storage applications. A comprehensive understanding of the ionic structure of these mixed salts is essential to elucidate the relationship between their structural arrangements and thermophysical properties. In this study, 35 Cl solid-state NMR spectroscopy was employed to provide detailed insights into the local structure of MgCl 2 −KCl mixed salts. By analyzing the quadrupolar interactions of the coordinated Cl − ions, specifically quadrupolar coupling constant (C Q ) and asymmetry parameter (η), the disruption of symmetry and the coordination of Cl − ions were characterized. The study confirmed a structural transformation from KCl to K 2 MgCl 4 , KMgCl 3 , and MgCl 2 phases as the concentration of MgCl 2 increased, resulting in changes of Cl − ionic coordination from 6-fold to 5-fold or 4-fold geometries. Such structural coordination changes will influence the lattice vibrational modes, and thus altering the thermophysical properties, such as heat capacity. These results offer a deeper understanding of the ionic structure and structural evolution of MgCl 2 −KCl mixed salts. Furthermore, the results highlight the utility of 35 Cl NMR spectroscopy as a powerful tool for investigating the microstructure and structural evolution of solid eutectic salts.

show abstract

Thermodynamic re-optimization of the ACl -MgCl2 (A=Na, K, Rb, Cs and Ca, x=1 or 2) systems

Cited by 2 publications

References 32 publications

New ultrafast scintillators with core valence luminescence: Cs₂MgCl₄ and Cs₃MgCl₅

New ultrafast scintillators with core valence luminescence: Cs₂MgCl₄ and Cs₃MgCl₅

Probing the Ionic Coordination in MgCl₂–KCl Mixed Salts by Quadrupolar ³⁵Cl NMR

Contact Info

Product

Resources

About

Thermodynamic re-optimization of the ACl -MgCl2 (A=Na, K, Rb, Cs and Ca, x=1 or 2) systems

Cited by 2 publications

References 32 publications

New ultrafast scintillators with core valence luminescence: Cs2MgCl4 and Cs3MgCl5

New ultrafast scintillators with core valence luminescence: Cs2MgCl4 and Cs3MgCl5

Probing the Ionic Coordination in MgCl2–KCl Mixed Salts by Quadrupolar 35Cl NMR

Contact Info

Product

Resources

About

New ultrafast scintillators with core valence luminescence: Cs₂MgCl₄ and Cs₃MgCl₅

New ultrafast scintillators with core valence luminescence: Cs₂MgCl₄ and Cs₃MgCl₅

Probing the Ionic Coordination in MgCl₂–KCl Mixed Salts by Quadrupolar ³⁵Cl NMR