Thermodynamic reassessment of the Cd−Zn system

Min, Seung-Kee; Jung, Woo-Gwang

doi:10.1007/bf03027879

Met. Mater. Int.

2007

DOI: 10.1007/bf03027879

|View full text |Cite

Thermodynamic reassessment of the Cd−Zn system

Seung-Kee Min

Woo-Gwang Jung

Abstract: The Cd-Zn system has been thermodynamically reassessed with the CALPHAD method by combining more recent experimental data, in particular the activities of zinc in the liquid phase. A good agreement is obtained between the calculated and experimental thermodynamic parameters as well as phase boundaries.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2018

2023

Publication Types

Select...

Article3

Relationship

Self Cite0

Independent3

Authors

Journals

Cited by 3 publications

References 23 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Thermodynamic Evaluation and Optimization of the As–Cd, As–Zn and As–Cd–Zn Systems

Kidari

Chartrand

2023

Metall Mater Trans B

View full text Add to dashboard Cite

In this work, a critical evaluation of all available phase diagrams and thermodynamic data for the As–Cd, As–Zn and As–Cd–Zn systems has been performed and thermodynamic assessments over the whole composition ranges are presented using the CALPHAD method. To predict thermodynamic properties and phase equilibria for these systems, the Modified Quasichemical Model for short range ordering was used for the liquid phase and the Compound Energy Formalism was used for the solid solutions. The optimized binary systems are in good agreement with existing experimental data. Within the ternary system predicted phase equilibria, the $${\text{ZnAs}}_{2}{-}{\text{CdAs}}_{2}$$ ZnAs 2 - CdAs 2 and $${{\text{Zn}}_{3}\text{As}}_{2}{-}{{\text{Cd}}_{3}\text{As}}_{2}$$ Zn 3 As 2 - Cd 3 As 2 sections are in good agreement with the experimental data. Also, the eutectic temperature is accurately optimized for $${\text{ZnAs}}_{2}{-}{{\text{Cd}}_{3}\text{As}}_{2}$$ ZnAs 2 - Cd 3 As 2 and $${{\text{Zn}}_{3}\text{As}}_{2}{-}{\text{CdAs}}_{2}$$ Zn 3 As 2 - CdAs 2 . However, the calculated liquidus of these two joins are less satisfactory compared to the experimental data. This is most likely due to the polymerization behavior of arsenic and its multivalence, which is not considered by the model used in this work.

show abstract

Thermodynamic Evaluation and Optimization of the As–Cd, As–Zn and As–Cd–Zn Systems

Kidari

Chartrand

2023

Metall Mater Trans B

View full text Add to dashboard Cite

show abstract

CALTPP: A general program to calculate thermophysical properties

Liu

Zhang

et al. 2020

Journal of Materials Science & Technology

View full text Add to dashboard Cite

Surface tension modelling of liquid Cd–Sn–Zn alloys

Fima

Novaković

2018

Philosophical Magazine

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

Thermodynamic reassessment of the Cd−Zn system

Cited by 3 publications

References 23 publications

Thermodynamic Evaluation and Optimization of the As–Cd, As–Zn and As–Cd–Zn Systems

Thermodynamic Evaluation and Optimization of the As–Cd, As–Zn and As–Cd–Zn Systems

CALTPP: A general program to calculate thermophysical properties

Surface tension modelling of liquid Cd–Sn–Zn alloys

Contact Info

Product

Resources

About