Thermodynamic studies on adsorption at interfaces. I. General formulation

Motomura, Kinsi

doi:10.1016/0021-9797(78)90371-5

Cited by 188 publications

(127 citation statements)

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“…According to a series of thermodynamic studies on adsorption at interfaces given by Motomura [15], variation in  for aqueous salt solution of a strong electrolyte which dissociates into  + cations and  -anions is given as a function of T, p and m; …”

Section: Methodsmentioning

confidence: 99%

Thermodynamic quantities of surface formation of aqueous electrolyte solutions X. Aqueous solution of 2:1 valence-type salts

Matubayasi¹,

Takayama²,

Ito³

et al. 2011

Journal of Colloid and Interface Science

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The behaviors of a series of calcium halides and of alkali earth metal chlorides in the air/water surface region were studied in comparison with those of alkali metal halides by measuring the surface tension increments of solutions. The effect of salts with divalent cation on the surface tension increments is pronounced than that of uni-univalent salts, but there are some similarities between these two types. It seems that the anions cause a marked effect on surface tension which is proportional to the magnitude of hydration in the bulk water. We also observed the decrease in the entropy change of surface formation with increasing concentration. The importance of electrical double layer at the surface was discussed in relation to these surface tension increments.

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Section: Methodsmentioning

confidence: 99%

Thermodynamic quantities of surface formation of aqueous electrolyte solutions X. Aqueous solution of 2:1 valence-type salts

Matubayasi¹,

Takayama²,

Ito³

et al. 2011

Journal of Colloid and Interface Science

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“…Assuming that the solution is ideal, the surface density of NaTDC, G H 1 , is calculated by use of the following equation in accordance with the thermodynamic treatment of Motomura (15)(16)(17):…”

Section: Methodsmentioning

confidence: 99%

Thermodynamic Studies of the Adsorbed Films and Micelles of Sodium Taurodeoxycholate

Matubayasi

Sugiyama

Kanzaki

et al. 1997

Journal of Colloid and Interface Science

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“…6a, the should be noted that the composition that appears in Eq. entropy of surface formation (D H W s, curve 1) is assigned to the two contributions: that from the entropies in the bulk solu- [17] is not x i but x s i . Then the right hand side of Eq.…”

Section: Entropy and Energy Of Surface Formationmentioning

confidence: 99%

Thermodynamic Study on the Surface Formation of the Mixture of Water and Ethanol

Aratono

Toyomasu

Villeneuve

et al. 1997

Journal of Colloid and Interface Science

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Thermodynamic studies on adsorption at interfaces. I. General formulation

Cited by 188 publications

References 1 publication

Thermodynamic quantities of surface formation of aqueous electrolyte solutions X. Aqueous solution of 2:1 valence-type salts

Thermodynamic quantities of surface formation of aqueous electrolyte solutions X. Aqueous solution of 2:1 valence-type salts

Thermodynamic Studies of the Adsorbed Films and Micelles of Sodium Taurodeoxycholate

Thermodynamic Study on the Surface Formation of the Mixture of Water and Ethanol

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