Thermodynamic study of the three isomers of bromo and iodobenzoic acids. Part II

Sabbah, Raphaël; Rojas-Aguilar, Aarón

doi:10.1007/bf02275165

Cited by 16 publications

(14 citation statements)

References 30 publications

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“…(22) Most of the literature values had been obtained by the classical method using a rotating-bomb calorimeter and a mass 10.8 g of substance for each combustion. Our new result is also in good agreement with our value: −(3065.5520.52) kJ·mol −1 , (17) obtained with an isoperibol rotating-bomb calorimeter and a mass 0.8 g of substance for each combustion.…”

Section: Resultssupporting

confidence: 90%

Combustion calorimetry on samples of mass about 5 mg of substances containing chlorine with a CRMT rocking-bomb calorimeter. Application to the study ofp-chlorobenzoic acid

Sabbah

Rojas-Aguilar

1995

The Journal of Chemical Thermodynamics

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Wishing to extend its possibilities, we have used the CRMT rocking calorimeter in association with a microbomb to determine the enthalpy of combustion of a sample of low mass (about 5 mg) of a substance containing chlorine. p-Chlorobenzoic acid, p-ClC6H4COOH, a candidate as reference material for combustion calorimetry of substances containing chlorine, has been investigated. The value−(3063.321.5) kJ·mol −1 for its molar enthalpy of combustion obtained with this apparatus is in good agreement with the authors' and literature values obtained by classical combustion calorimetry.

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Section: Resultssupporting

confidence: 90%

Combustion calorimetry on samples of mass about 5 mg of substances containing chlorine with a CRMT rocking-bomb calorimeter. Application to the study ofp-chlorobenzoic acid

Sabbah

Rojas-Aguilar

1995

The Journal of Chemical Thermodynamics

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“…n Generated from heat capacity measurements reported by Ueberreiter and Orthmann (1950) under the form of a linear equation. o Sabbah and Rojas Aguilar (1996).…”

Section: Solubility Datamentioning

confidence: 96%

“…Carson et al (1993Carson et al ( , 1994 also report experimental values for the enthalpies of formation at 25°C and 1 bar of liquid diiodomethane (XII), 1,3-diiodopropane (XIV), and 1,4-diiodobutane (XV), as well as of crystalline triiodomethane (XVIII), tetraiodomethane (XIX), and 1,2-diiodoethane (XIII). Sabbah and Rojas Aguilar (1996) have redetermined the standard molal enthalpies of formation of crystalline 2-, 3-, and 4-iodobenzoic acids (XXXVI-XXXVIII) and obtained values significantly different from the previous recommended values of Cox and Pilcher (1970), which were calculated from standard molal enthalpies of combustion reported by Smith (1956).…”

Section: Enthalpies Of Formationmentioning

confidence: 99%

Thermodynamic properties of organic iodine compounds

Richard¹,

Gaona

2011

Geochimica et Cosmochimica Acta

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“…The previously reported tendency to increasing degree of halogen aggregation (here called ''Halaggregation'') in the sequence F \ Cl B Br B I was confirmed. While the enthalpy of formation of all the 12 HBAs have long been known in the condensed phase as found in our organic thermochemical archive [200], it is only rather recently that sublimation enthalpies are available for all of them [201] to allow a bridge between these structural chemistry studies and thermochemistry with multiply reinvestigated species [202,203].…”

Section: Issuementioning

confidence: 99%

Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline

Ponikvar

Liebman

2008

Struct Chem

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In this study, we relate the contents of the journal Structural Chemistry for the calendar year 2007 and thermochemistry. The year's articles were briefly summarized and a thermochemical comment written to supplement them. Frequently questions were asked and future research was suggested.Keywords Structural Chemistry Á Thermochemistry Á Thermodynamics Á Enthalpy of formation Á Enthalpy of phase change Á Enthalpy of reaction As practiced disciplines, structural chemistry and thermochemistry are very often unrelated. In this study, these disciplines are linked as relations are explicitly made using the contents of the journal Structural Chemistry (Vol. 18) for the calendar year 2007 as a scaffold for our analysis, for our selected articles in the discipline of structural chemistry. These studies have been reviewed by us, where we give them a thermochemical flavor. While this commentary is most generally written in terms of brief summaries of literature papers involving enthalpies of formation and/or reaction, not uncommonly we raise questions and even suggest possible future research. We are not, however, going to give a thermochemical slant on book reviews, honorary dedications, and obituaries although these works will be cited in our text.As such, this article is a sequel to our earlier related reviews of Structural Chemistry for the calendar years 2000 through 2004 [1-5]. Reviews for 2005 and 2006 are currently being prepared. Issue 1In the first article in the first issue of Structural Chemistry for 2007, Hargittai [6] asserted that while research is currently usually carried out in big groups, the most important ideas, observations and discoveries still belong to individuals who have to bring down dogmas or open entirely new areas in science. This may bring solace to the thermochemical community in which research groups are generally small, and the number of new practitioners sadly few.In the past decade, the crystal engineering of multidimensional arrays and networks containing metal ions has achieved considerable progress because of the increased interest in the potential utility of these compounds as zeolite-like materials [7-11], catalysts [12], or magnetic materials [13][14][15]. The thermochemistry of these species is complicated by their inherent complexity: however, estimation approaches of their key thermochemical quantities are increasingly reliable [16]. In the second article of this issue, by Wang et al. [17], the versatility of malonate dianion as a ligand for the construction of extended networks with different topologies dependent on the coordination geometry of the metal ion was discussed. The synthesis and structure of a novel malonate-bridged copper(II) compound in which copper(II) ions have two different coordination environments in a novel three-dimensional (3D) network was described. Metal malonates have been studied from a

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Thermodynamic study of the three isomers of bromo and iodobenzoic acids. Part II

Cited by 16 publications

References 30 publications

Combustion calorimetry on samples of mass about 5 mg of substances containing chlorine with a CRMT rocking-bomb calorimeter. Application to the study ofp-chlorobenzoic acid

Combustion calorimetry on samples of mass about 5 mg of substances containing chlorine with a CRMT rocking-bomb calorimeter. Application to the study ofp-chlorobenzoic acid

Thermodynamic properties of organic iodine compounds

Interplay of thermochemistry and Structural Chemistry, the journal (volume 18, 2007) and the discipline

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