Thermodynamics and activity coefficients at infinite dilution for organic solutes, water and diols in the ionic liquid choline bis(trifluoromethylsulfonyl)imide

Activity coefficients at infinite dilution and physicochemical properties for organic solutes and water in the ionic liquid 4-(3-hydroxypropyl)-4-methylmorpholinium bis(trifluoromethylsulfonyl)-amide

“…It is caused by asymmetric structure of [NTf 2 ] À anion with exposed nitrogen atom, which stronger interacts with [N-C 3 OHmMOR] + cation having both of oxygen atom in the ring and hydroxyl group in alkyl chain than with [N-C 3 [1][2][3][4][5][6][7][8][9][10][11][12][13][16][17][18][19][20][21][22][23][24][25][26]. The names and the structures of used abbreviation of IL cations are explained in table 2S.…”

“…This work is a continuation of measurements of activity coefficients at infinity dilution for ILs based on bis(trifluoromethylsulfonyl)-amide, [NTf 2 ] À [1][2][3][4][5][6][7][8][9][10][11][12][13]. Previous papers have shown high selectivity of selected separation problems for 1-(3-hydroxypropyl)pyridinium, [N-C 3 OHPY] + and 4-(3-hydroxyethyl)-4-methylmorpholinium, [COC 2 mMOR] + based ILs [1,2].…”

“…Selectivity, S versus capacity, k for ionic liquids [NTf 2 ] À anions in extraction of heptane/thiophene problem at T = 318.15 K[1][2][3][4][5][6][7][8][9][10][11][12]14].…”

“…) and compared with the values for http://dx.doi.org/10.1016/j.jct.2015.02.024 0021-9614/Ó 2015 Elsevier Ltd. All rights reserved.other available in the literature [NTf 2 ] À based ILs[1][2][3][4][5][6][7][8][9][10][11][12][13][16][17][18][19][20][21][22][23][24][25][26]. Additionally, (gas + liquid) partition coefficients, K L for these systems were determined and the partial molar excess Gibbs free13 values obtained over the temperature range.…”

Activity coefficients at infinite dilution for organic solutes and water in 1-ethyl-1-methylpyrrolidinium lactate

“…The values of activity coefficients at infinite dilution of a solute in the IL provide the basic information on the intermolecular interaction between solute and the IL. The lowest values are usually observed for alkynes, polar substances as alcohols, ketones or ethers which is a result of hydrogen bonding, the pAp, nAp, or other strong interactions [12,[16][17][18].…”