2004
DOI: 10.1016/j.molliq.2003.09.003
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Thermodynamics of binary liquid mixtures: application of the Prigogine–Flory–Patterson theory to excess molar volumes of acetonitrile+1-alkanol systems

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Cited by 42 publications
(30 citation statements)
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“…The j T values for MeCN and MeOH have been reported in some of the studied temperatures in the literature [19], which have good agreement with their calculated values from equation (12). Gu …”
Section: Excess Molar Volumesupporting
confidence: 79%
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“…The j T values for MeCN and MeOH have been reported in some of the studied temperatures in the literature [19], which have good agreement with their calculated values from equation (12). Gu …”
Section: Excess Molar Volumesupporting
confidence: 79%
“…In recent years, PFP theory (which is applied to both nonpolar and polar molecules present in the mixtures) has been successfully used for theoretical analysis of the excess thermodynamic functions of binary liquid mixtures [16,19,20,27]. In this paper, we have applied PFP theory for prediction of the V E values of four binary (ionic liquid + MeCN or MeOH) systems at T = (298.15 to 318.15) K. According to PFP theory, V E is presented as the sum of three contributions: an interactional contribution V E ðint.Þ , a free volume one V E ðfv.Þ and that of internal pressure contribution V E ðP ÃÞ .…”
Section: Excess Molar Volumementioning
confidence: 99%
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“…known from the literature [1][2][3][4][5]. The molar excess volumes, V E m [7][8][9][10][11][12][13][14][15][16][17] and molar excess enthalpies, H E m [18,19] for (alkan-1-ol + acetonitrile) systems were presented previously. The molar excess volumes, V E m for [alkan-1-ol (methanol, ethanol, propan-1-ol) + benzonitrile] are all relatively small and negative (lower than 0.4 cm 3 mol −1 ) indicating small structural effects, are not symmetric and have minima occurring near x(alkan-1-ol) = 0.6 [20].…”
Section: Introductionmentioning
confidence: 99%