Thermodynamics of Cesium Molybdate-Based Single Crystals: Standard Enthalpy of Formation, Lattice Enthalpy, and Heat Capacity

Matskevich, N. I.; Semerikova, A. N.; Trifonov, V. A.; Samoshkin, D. A.; Chernov, A. A.; Stankus, S. V.; Luk’yanova, S. A.; Shlegel’, V. N.; Zaitsev, V. P.; Kuznetsov, V. A.

doi:10.1134/s0036023622602331

Russ. J. Inorg. Chem.

2023

DOI: 10.1134/s0036023622602331

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Thermodynamics of Cesium Molybdate-Based Single Crystals: Standard Enthalpy of Formation, Lattice Enthalpy, and Heat Capacity

N. I. Matskevich,

A. N. Semerikova,

V. A. Trifonov

et al.

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2024

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Cited by 2 publications

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Thermodynamic Characteristics of the Sodium Dimolybdate Single Crystal: Enthalpy and Heat Capacity

Matskevich,

Semerikova,

Grigor’eva

et al. 2024

Russ. J. Phys. Chem.

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Thermodynamic Characteristics of the Sodium Dimolybdate Single Crystal: Enthalpy and Heat Capacity

Matskevich,

Semerikova,

Grigor’eva

et al. 2024

Russ. J. Phys. Chem.

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Термодинамические Характеристики Монокристаллического Димолибдата Натрия: Энтальпии, Теплоемкость

Мацкевич,

Семерикова,

Григорьева

et al. 2024

Russian Journal of Physical Chemistry

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Стандартная энтальпия образования димолибдата натрия определена методом калориметрии растворения на основании измеренных энтальпий растворения Na2CO3, MoO3, Na2Mo2O7 в 0.2 M растворе NaOH и литературных данных: ∆fH0(Na2Mo2O7, 298.15 K) = −2245.3 ± 6.3 кДж/моль. С использованием цикла Борна–Габера рассчитана энтальпия решетки: –54730 кДж/моль. Показано, что длина волны люминесцентного излучения уменьшается от 650 нм до 540 нм при переходе от молибдата натрия к вольфрамату натрия, при этом энтальпия решетки уменьшается от –54730 кДж/моль (Na2Mo2O7) до –49030 кДж/моль (Na2W2O7). Температурная зависимость теплоемкости димолибдата натрия определена в области температур 320–785 K. Показано, что в этом интервале отсутствуют фазовые переходы.

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Thermodynamics of Cesium Molybdate-Based Single Crystals: Standard Enthalpy of Formation, Lattice Enthalpy, and Heat Capacity

Cited by 2 publications

References 35 publications

Thermodynamic Characteristics of the Sodium Dimolybdate Single Crystal: Enthalpy and Heat Capacity

Thermodynamic Characteristics of the Sodium Dimolybdate Single Crystal: Enthalpy and Heat Capacity

Термодинамические Характеристики Монокристаллического Димолибдата Натрия: Энтальпии, Теплоемкость

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