Thermodynamics of HCl in water—ethylene carbonate mixtures

El-Harakany, A. A.; Sadek, H.; Abdou, A.M.

doi:10.1016/0013-4686(81)85145-6

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Free Energies Of Transfer Of Simple Cations and Anions1

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1987

2022

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“…solvent composition using the data of ref. (17). AG,"(HCl), on the molality scale is then given by ( 14) AG,"(HCl), = 96.…”

Section: Free Energies Of Transfer Of Simple Cations and Anionsmentioning

confidence: 99%

Ionic solvation in water–cosolvent mixtures. Part 14.—Free energies of transfer of single ions from water into water–ethylene carbonate and water–propylene carbonate mixtures

Groves¹,

Halawani²,

Wells³

1987

J. Chem. Soc., Faraday Trans. 1

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The spectrophotometric solvent-sorting method for determining the free energies of transfer for individual ions, AG:(i), from water into a mixture of water and cosolvent has now been applied to cosolvents which increase the dielectric constant and enhance the solvent structure when added in small concentrations to water. The spread of AGY(i) values found, uiz. AG:(i) for i = a cation is negative and AG;(i) for i = an anion is positive, is similar to those found in mixtures where the cosolvent decreases the dielectric constant and enhances the solvent structure or increases the dielectric constant and decreases the solvent structure. Values for AG:(i)e, the free energy of transfer of the charge alone, are found for some large organic anions.

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“…solvent composition using the data of ref. (17). AG,"(HCl), on the molality scale is then given by ( 14) AG,"(HCl), = 96.…”

Section: Free Energies Of Transfer Of Simple Cations and Anionsmentioning

confidence: 99%