Thermodynamics of monolayers

Kemball, C.; Rideal, Eric K.; Guggenheim, E. A.

doi:10.1039/tf9484400948

Cited by 83 publications

(33 citation statements)

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“…where P 0 = 101.325 kPa is the standard pressure for the gas phase, and π 0 = 0.06084 mN m -1 is the corresponding state standard surface pressure proposed by Kemball and Rideal [4], and γ σ i is included to consider nonideality in the surface phase. The Kemball-Rideal standard state is the two-dimensional equivalent of an ideal gas standard state [4].…”

Section: Thermodynamics Of Adsorption At the Air-water Interfacementioning

confidence: 99%

Trace gas adsorption thermodynamics at the air−water interface: Implications in atmospheric chemistry

Valsaraj

2009

Pure and Applied Chemistry

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The thermodynamics of adsorption of gaseous organic compounds such as polycyclic aromatic hydrocarbons (PAHs) on water films is reviewed and discussed. The various experimental methods available to determine the thermodynamic equilibrium constant and the structure-activity relationships to correlate and estimate the same are reviewed. The atmos pheric implications of the adsorption and oxidation of PAHs at the air-water interface of thin films of water such as existing in fog droplets, ice films, and aerosols are also enumerated.

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Section: Thermodynamics Of Adsorption At the Air-water Interfacementioning

confidence: 99%

Trace gas adsorption thermodynamics at the air−water interface: Implications in atmospheric chemistry

Valsaraj

2009

Pure and Applied Chemistry

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“…The pressure at standard state is defined as 1 atm and the gas at standard state is assumed to be ideal gas [25]. As the interfacial tension at standard state does not vary with pressure, Eq.…”

Section: Surface Free Energy Of Adsorption For Methanementioning

confidence: 99%

Interfacial properties of methane/aqueous VC-713 solution under hydrate formation conditions

Peng¹,

Sun²,

Liu³

et al. 2009

Journal of Colloid and Interface Science

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“…We note that the proposed model automatically satisfies the thermodynamic consistency relation [14,15] oqQcd "~ ( OQzn O Uz.) Ccd = t, i-ffU ) Oz.'…”

Section: Construction Of Adsorption Isotherms From Batch Experimentsmentioning

confidence: 99%

Quantitative description of multi-component reactive transport in porous media: An empirical approach

et al. 1996

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We propose a general method for the description of multi-component reactive transport in porous media. The approach is based on the local equilibrium assumption and consists of four steps: (i) measurement of the adsorbed amounts of all components of interest by means of laboratory batch experiments, (ii) construction of a simple, empirical binding model consistent with the experimental data by means of constrained, regularized least-squares, (iii) calculations of multi-component breakthrough curves based on numerical solutions of the transport equations coupled to the empirical binding model, (iv) verification of these model predictions with laboratory column experiments. We demonstrate the applicability of the procedure by investigating simultaneous transport of cadmium and zinc at constant pH in a silica sand column.

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Thermodynamics of monolayers

Cited by 83 publications

References 0 publications

Trace gas adsorption thermodynamics at the air−water interface: Implications in atmospheric chemistry

Trace gas adsorption thermodynamics at the air−water interface: Implications in atmospheric chemistry

Interfacial properties of methane/aqueous VC-713 solution under hydrate formation conditions

Quantitative description of multi-component reactive transport in porous media: An empirical approach

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