Thermodynamics-of Precipitation of Silver Laurate From Aqueous Solution*

Thermochemistry of dissolution of sodium alkylsulfonates

“…It was found for several systems, such as silver laurate [9] and barium dodecylsulfate [11], that the heat capacity increases in the course of the dissolution process. It was found for several systems, such as silver laurate [9] and barium dodecylsulfate [11], that the heat capacity increases in the course of the dissolution process.…”

“…In the second step, both calorimetry and solubility data are combined to give the entropy at the reference temperature [9][10][11]. In the first step, one would obtain the heat capacity change and the standard enthalpy at the reference temperature from the dependency of enthalpy on temperature.…”

“…In principle, the heat of dissolution can be obtained either from the temperature dependency of the solubility [1][2][3][4][5][6][7][8][9], or by calorimetry measurements [7][8][9][10][11]. The solubility method requires constant enthalpy and entropy over the temperature range of interest.…”

“…The solubility method requires constant enthalpy and entropy over the temperature range of interest. In order to evaluate thermodynamic parameters, one needs to perform both calorimetry and solubility measure-merits [9][10][11]. If the heat capacity change in the course of a reaction is negligible, the enthalpy and entropy do not depend on the temperature.…”