1998
DOI: 10.1524/ract.1998.81.4.189
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Thermodynamics of Synergistic Extraction of Americium(III) with HTTA using DHD£CMP(Bi-functional) and TBP(Mono-functional)

Abstract: Synergism / Am(ni) / HTTA / DHDECMP / TBP / ThermodynamicsSuininary Synergistic extraction of Ani(in) was studied with HTTA in combination with bifunctional (DHDECMP) and mono-functional (TBP) neutral donors in benzene medium at various fixed temperatures. The equilibrium constant (log K^) for the organic phase synergistic reaction with DHDECMP was found to be higher by about two Orders of magnitude as compared to that with TBP, in spite of their comparable basicities. This indicated the bi-functional behaviou… Show more

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“…18-crown-6 and 15-crown-5 [12][13][14]. For instance, the stoichiometry of the complex between PuO 2 2+ and…”
Section: Solvent Extraction Research and Development Japan Vol 17mentioning
confidence: 99%
“…18-crown-6 and 15-crown-5 [12][13][14]. For instance, the stoichiometry of the complex between PuO 2 2+ and…”
Section: Solvent Extraction Research and Development Japan Vol 17mentioning
confidence: 99%