2011
DOI: 10.3390/e13081481
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Thermodynamics of Thermoelectric Phenomena and Applications

Abstract: Abstract:Fifty years ago, the optimization of thermoelectric devices was analyzed by considering the relation between optimal performances and local entropy production. Entropy is produced by the irreversible processes in thermoelectric devices. If these processes could be eliminated, entropy production would be reduced to zero, and the limiting Carnot efficiency or coefficient of performance would be obtained. In the present review, we start with some fundamental thermodynamic considerations relevant for ther… Show more

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Cited by 275 publications
(278 citation statements)
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“…we note that the optimal entropy flow rate ex o S is equal to half of the cutoff entropy flow rate ex sc S in the case of an exo-reversible heat engine which recalls a well-known result in the field of thermoelectric conversion [46]. By injecting the optimal entropy flow rate in (7), we obtain the expression of maximum output power of the exo-reversible heat engine:…”
Section: Determination Of the Maximum Mechanical Power And The Associmentioning
confidence: 69%
See 1 more Smart Citation
“…we note that the optimal entropy flow rate ex o S is equal to half of the cutoff entropy flow rate ex sc S in the case of an exo-reversible heat engine which recalls a well-known result in the field of thermoelectric conversion [46]. By injecting the optimal entropy flow rate in (7), we obtain the expression of maximum output power of the exo-reversible heat engine:…”
Section: Determination Of the Maximum Mechanical Power And The Associmentioning
confidence: 69%
“…This is again a well-known result in the field of thermoelectric conversion [46]. The optimal electric current is defined by:…”
Section: Determination Of the Maximum Mechanical Power And The Associmentioning
confidence: 70%
“…When treating the extensive variables entropy S and electrical charge q equal in rank, the description of the thermoelectric effect by the Onsager-de Groot-Callen model (see Callen (2012), Goupil et al (2011)) takes a highly symmetric form:…”
mentioning
confidence: 99%
“…2) will have an even more rudimentary form. Remember, instead of the entropy per charge carrier S Ã , widely the Seebeck coefficient α is used to describe the material's property, which has then the meaning of entropy transported per unit charge; see Scott (1962), Goupil et al (2011):…”
mentioning
confidence: 99%
“…This is considered in detail by Gray [2] and Iordanishvili and Babin [4]. Goupil [5,6] studied non-stationary operation with Onsager approach and calculates for thermoelectric device the important parameters for transient regimes: time constant τ and capacitance C.…”
Section: Quasi-stationary Thermoelectricitymentioning
confidence: 99%