2006
DOI: 10.1016/j.jssc.2006.03.030
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Thermoelectric properties of homologous p- and n-type boron-rich borides

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Cited by 91 publications
(78 citation statements)
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“…[4][5][6][7] Promising thermoelectric properties have also been observed in boron-rich borides containing B 12 icosahedra. 8,9 Compounds built from clusters of boron icosahedra have intrinsically low thermal conductivity. [10][11][12] The rare earth borocarbonitrides have been reported to be a potential n-type counterpart 8,9,13 to boron carbide 14,15 as high temperature thermoelectric materials.…”
mentioning
confidence: 99%
See 1 more Smart Citation
“…[4][5][6][7] Promising thermoelectric properties have also been observed in boron-rich borides containing B 12 icosahedra. 8,9 Compounds built from clusters of boron icosahedra have intrinsically low thermal conductivity. [10][11][12] The rare earth borocarbonitrides have been reported to be a potential n-type counterpart 8,9,13 to boron carbide 14,15 as high temperature thermoelectric materials.…”
mentioning
confidence: 99%
“…8,9 Compounds built from clusters of boron icosahedra have intrinsically low thermal conductivity. [10][11][12] The rare earth borocarbonitrides have been reported to be a potential n-type counterpart 8,9,13 to boron carbide 14,15 as high temperature thermoelectric materials. The rare earth aluminoborides have also been attracting increasing attention.…”
mentioning
confidence: 99%
“…8). 47),49) Thus, this compound can be regarded as being homeotypic to Al 5 C 3 N. The layer stacking sequences are <BABBABBAB>, <BBABBABBA> and/or <ABBABBABB> for the three types of domains of (Al,Si) 6 (O,C,N) 5 (space group R 3m and Z = 3), which is homeotypic to Al 6 C 3 N 2 . 48) In a similar manner, the layered oxycarbonitrides with the chemical formulas (Al,Si) 7 (O,C,N) 6 and (Al,Si) 8 (O,C,N) 7 are also homeotypic to, respectively, Al 7 C 3 N 3 and Al 8 C 3 N 4 .…”
Section: Microscopymentioning
confidence: 87%
“…The detailed atom arrangement in (Al,Si) 8 (O,C,N) 7 is still uncertain. 50) The dimensions of the domains would be within the coherence range of X-rays, hence the crystal structures were successfully represented by the split-atom models.…”
Section: Microscopymentioning
confidence: 99%
“…In addition, novel boron icosahedra cluster compounds like RB 44 Si 2 (R = rare earth) [9][10][11][12], B 6 S 1-x [13] are being investigated. Rare earth borocarbonitrides, RB 22 C 2 N, RB 17 CN and RB 28.5 C 4 , were discovered to be the first boron icosahedra cluster containing compounds that exhibit intrinsic n-type thermoelectric materials [14,15]. Some of the recently discovered novel borides have been found not to be easy to obtain dense samples, and various studies to remedy this have been carried out; for example, mechanical grinding and sintering the sample through the spark plasma sintering (SPS) treatment with sintering aids such as metals, rare earth tetra brides and carbides [16][17][18][19].…”
Section: Introductionmentioning
confidence: 99%