“…Direct M–M bonds are most commonly found in early 4d and 5d transition metals (with M = Mo, Re, or Ru) that have a small number of electrons in d-orbitals (d 1 –d 4 ). Some examples include the compounds LnMo 8 O 14 (Ln = La, Ce, Pr, Nd, Sm), , LnMo 5 O 8 (Ln = La, Ce, Pr, Nd, Sm, Eu, Gd), Nd 4 Re 2 O 11 , Ln 4 Re 6 O 19 (Ln = La, Pr, Nd), and La 4 Ru 6 O 19 . , The clearest signature of direct M–M bonds is the short distances between the metal participating in the bonding, as these bond lengths are far shorter than the M–M distances that are typically seen for the same compounds in the absence of M–M bonding (>3 Å). The shortest M–M bond distance reported is a Cr–Cr bond, 1.8028(9) Å, found in a molecular dinuclear chromium diazadiene complex .…”