1997
DOI: 10.1016/s0013-4686(96)00337-4
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Thermoelectrochemical impedance

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Cited by 19 publications
(26 citation statements)
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“…In this case, the same order of magnitude is obtained for the free convection and the thermal convection, and experiments can be performed with a sufficient accuracy. In particular, the general relationship 19 between the TEC impedance measured in potentiostatic regulation, in galvanostatic regulation, and the usual electrochemical impedance 12,14,16 was verified. Rotenberg 16,17 had developed a theoretical prediction for TEC, but the experimental part of his work was too poor to permit a quantitative approach.…”
mentioning
confidence: 77%
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“…In this case, the same order of magnitude is obtained for the free convection and the thermal convection, and experiments can be performed with a sufficient accuracy. In particular, the general relationship 19 between the TEC impedance measured in potentiostatic regulation, in galvanostatic regulation, and the usual electrochemical impedance 12,14,16 was verified. Rotenberg 16,17 had developed a theoretical prediction for TEC, but the experimental part of his work was too poor to permit a quantitative approach.…”
mentioning
confidence: 77%
“…In particular, the general relationship 19 between the TEC impedance measured in potentiostatic regulation, in galvanostatic regulation, and the usual electrochemical impedance 12,14,16 was verified. Rotenberg 16,17 had developed a theoretical prediction for TEC, but the experimental part of his work was too poor to permit a quantitative approach. Recently, electrochemical impedance of laminar free convection and thermal convection at a vertical electrode was studied 14,20 and a theoretical derivation was presented, based on the work of Marchiano and Arvia, 5 which used Levich's approach.…”
mentioning
confidence: 77%
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“…6, the low frequency loop is related to the mass transport process and the accumulation real point is related to the diffusion coefficient modifications due to the temperature modulation. According to Rotenberg [13] the high frequency branch may be related to the modification of the space charge in the double layer region due to the temperature modulation. The diagrams shape is the same as that obtained by using a reversible electrochemical system limited by mass transport (e.g.…”
Section: Tec Transfer Function Measured At the Limiting Currentmentioning
confidence: 99%
“…Indeed, greater attention has been devoted to the effects of the heated electrode and its temperature modification, either for stationary or dynamic regimes [5][6][7][8][9][10][11][12][13][14][15][16] by modulating the electrode temperature [10][11][12][13] or using temperature jump techniques [14,15].…”
Section: Introductionmentioning
confidence: 99%