2024
DOI: 10.1007/s10973-023-12868-w
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Thermogravimetric analysis and kinetic modeling of the pyrolysis of different biomass types by means of model-fitting, model-free and network modeling approaches

Olivier Fischer,
Romain Lemaire,
Ammar Bensakhria

Abstract: This work aims at comparing the ability of 7 modeling approaches to simulate the pyrolysis kinetics of spruce wood, wheat straw, swine manure, miscanthus and switchgrass. Measurements were taken using a thermogravimetric analyzer (TGA) with 4 heating rates comprised between 5 and 30 K min−1. The obtained results were processed using 3 isoconversional methods (Kissinger–Akahira–Sunose (KAS), Ozawa–Flynn–Wall (OFW) and Friedman), 1-step and 3-step Kissinger models, as well as an advanced fitting method recently … Show more

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