a b s t r a c tNanoparticles of pure yttrium oxide (Y 2 O 3 ) have been prepared by sol gel method. The powder X-ray diffraction (PXRD) pattern of as synthesized sample showed the amorphous nature. The as synthesized Y 2 O 3 powders are annealed at 500, 600, 700, 800 and 900°C for 2 h. Y 2 O 3 powder heat treated for 600°C showed cubic phase and the crystallite sizes are found to be $13 nm. Fourier transformed infrared spectroscopy (FTIR) revealed absorption with peaks at 3434, 1724, 1525, 1400, 847, 562 and 465 cm À1 . Photoluminescence (PL) of 100 MeV Si 8+ ion irradiated samples shows emission with peaks at 417, 432, 465 nm. It is found that PL intensity increases with increasing in ion fluence up to $3 Â 10 12 ions cm À2 and then decreases with further increase in ion fluence. A well resolved thermoluminescence (TL) glow with peak at $430 K (Tm 1 ) and an unresolved TL glow with peak at $538 (Tm 2 ), 584 K (Tm 3 ) are observed in ion irradiated samples.