Thermomechanical and thermogravimetric analysis of blends of poly (vinyl chloride) (PVC) with maleic anhydride–allyl propionate copolymer

Boztuğ, Ali; Zengin, Hacı Bayram; Basan, Satılmış

doi:10.1016/j.molstruc.2004.02.032

Cited by 17 publications

(11 citation statements)

References 21 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…There is a large amount of literature on different copolymers of MA used as a compatibilizer in the obtained blends of compatible polymer 12–17. In our laboratory, copolymers of MA are currently used as reactive polymers in the preparation of the compatible polymer blends via the MA moiety 18…”

Section: Introductionmentioning

confidence: 99%

Preparation of compatible blends of poly(methyl methacrylate) used in dentistry with a reactive terpolymer containing maleic anhydride and their thermomechanical characterization

Boztuğ

Coskun

Bolayır

et al. 2006

J of Applied Polymer Sci

View full text Add to dashboard Cite

This study focuses on the preparation of compatible blends with the poly(methyl methacrylate) (PMMA) using a reactive terpolymer maleic anhydridestyrene-vinyl acetate (MA-St-VA). In the first series of experiments, binary blends of the PMMA and the MA-St-VA terpolymer have been prepared in tetrahydrofurane. The PMMA and the MA-St-VA terpolymer formed the compatible blends. The effects on thermomechanical properties of MA-St-VA terpolymer ratio in the blends were studied. The glass transition temperatures (T g ), thermal expansion coefficient (␣), and other thermomechanical parameters for the blends have been established by TMA method and the compatibility of two polymers has been evaluated by these TMA parameters. The addition of MA-St-VA terpolymer to PMMA made a plasticizing effect on PMMA. This effect regularly changed with the increasing of the terpolymer in the blends.

show abstract

Section: Introductionmentioning

confidence: 99%

Preparation of compatible blends of poly(methyl methacrylate) used in dentistry with a reactive terpolymer containing maleic anhydride and their thermomechanical characterization

Boztuğ

Coskun

Bolayır

et al. 2006

J of Applied Polymer Sci

View full text Add to dashboard Cite

show abstract

“…7 In many studies, different copolymers of MA have been used as a compatibiliser to obtain the compatible blends. [8][9][10][11][12][13][14] Binary or ternary blends based on PVC have received tremendous attention in industrial applications owing to the combination of excellent mechanical properties and process ability of these blends. [15][16][17][18] The next logical extension of the binary interaction model is the analysis of binary blends in which one of the polymers is a terpolymer made up of three different repeat unit types.…”

Section: Introductionmentioning

confidence: 99%

Effects of reactive terpolymer containing maleic anhydride on thermomechanical properties of poly(vinyl chloride) based multicomponent blends

Boztuğ¹,

Yılmaz²

2007

Materials Research Innovations

View full text Add to dashboard Cite

In the present paper, the effects of reactive terpolymer containing maleic anhydride on the thermomechanical properties of PVC were investigated. The thermomechanical behaviour of multicomponent blend based on poly(vinyl chloride) (PVC), PVC/maleic anhydride-stryrenemethyl metacrylate (MA-St-MMA)/n-pentyl maleat-styrene-methyl metacrylate(nPnMA-St-MMA) were studied using the TMA method. The blends were prepared by changing the weight ratio of MA-St-MMA and nPnMA-St-MMA terpolymers, and keeping the PVC content fixed at 75 wt-%. The MA-St-MMA terpolymer, a reactive copolymer, formed the compatible blends with PVC. Results indicated that the elastic properties of PVC could be controlled by the MA-St-MMA terpolymer.

show abstract

“…A lot of terpolymers in this direction have been synthesised and used in different fields. [1][2][3][4][5][6] The synthesis of new polymers in polymer science is very much important. One of the methods of obtaining new materials is graft copolymerisation.…”

Section: Introductionmentioning

confidence: 99%

Modification and characterisation of terpolymer maleic anhydride–styrene–vinyl acetate by poly(ethylene adipate) copolymer

Boztuğ¹

2007

Materials Research Innovations

View full text Add to dashboard Cite

In the present paper, poly(ethylene adipate) (PEA) copolymer of ethylene glycol/adipic acid was synthesised by the polycondensation in the status without an initiator at 180uC for 5 h. It reacted with the PEA copolymer with maleic anhydride-styrene-vinyl acetate (MA-St-VA) terpolymer without using an initiator at 150uC for 6 h. Thus, MA-St-VA terpolymer was modified by the ring opening method. The original MA-St-VA terpolymer and the modified terpolymer were characterised by Fourier transform infrared spectroscopy (FTIR), thermomechanical analysis (TMA) and the viscosimetric method. It was observed that the modified terpolymer was more elastic than the original terpolymer.

show abstract

Thermomechanical and thermogravimetric analysis of blends of poly (vinyl chloride) (PVC) with maleic anhydride–allyl propionate copolymer

Cited by 17 publications

References 21 publications

Preparation of compatible blends of poly(methyl methacrylate) used in dentistry with a reactive terpolymer containing maleic anhydride and their thermomechanical characterization

Preparation of compatible blends of poly(methyl methacrylate) used in dentistry with a reactive terpolymer containing maleic anhydride and their thermomechanical characterization

Effects of reactive terpolymer containing maleic anhydride on thermomechanical properties of poly(vinyl chloride) based multicomponent blends

Modification and characterisation of terpolymer maleic anhydride–styrene–vinyl acetate by poly(ethylene adipate) copolymer

Contact Info

Product

Resources

About