Recycled soda lime silica glass‐filled polytetrafluoroethylene composites were prepared for substrate application at microwave frequencies. Various volume fractions (0.05–0.25) of the filler were dispersed in the polytetrafluoroethylene matrix. The composites’ dielectric, mechanical, and thermal properties were examined with respect to the filler content. X‐ray diffraction data established the phase structure of the polytetrafluoroethylene matrix and recycled soda lime silica glass. Scanning electron microscope micrographs revealed uniform filler distribution at lower recycled soda lime silica contents, while energy dispersive x‐ray analysis showed the purity of the composites. The tensile strength of the composites reduced from 13.5 MPa to 4.26 MPa, while the moisture absorption and density raised from 0.07 % and 2.195 g/cm3 to 0.19 % and 2.228 g/cm3 when the recycled soda lime silica filler volume fraction was adjusted from 0.05–0.25. The lowest coefficient of thermal expansion values was recorded at 0.25 % recycled soda lime silica volume fraction, which increased from 31.12 ppm/°C to 68.32 ppm/°C at 40 °C to 200 °C. At 0.05 filler volume fraction, the respective values of
ϵ'
${\varepsilon{} { {^\prime}}}$
,
tanδ
${tan\delta }$
and
Td
${{T}_{d}}$
of the composites decreased from 2.20, 0.0017, and 29.69 ps to 2.15, 0.0015, and 29.35 ps in the 8.2 GHz–12.4 GHz range.