In this paper, the finite element analysis was firstly employed to investigate the thermal analysis on two fireproof sealing models with ANSYS software under HC standard temperature-time condition. The main thermal parameters were analyzed and obtained, including temperature field, thermal flux, and thermal gradient. After comparing the two fireproof sealing models, the major conclusions are summarized as follows: In terms of temperature field, the temperature on the left side of the first model ranges from 60 to 524°C in. In contrast, the highest temperature on the left side of the second model eventually reaches below 151°C. Moreover, the vectors of thermal gradient in the first model are compared with the second model, and the temperature gradient disturbance is more obvious in the second fireproof sealing model, which is better to slow down temperature spreading. The accelerated speed of E1 and G1 is 0.0096°C/s and 0.0619°C/s partly, which are far more than C2 and F2 with values of 0.0028°C/s and 0.0078°C/s, respectively. In a word, the performance of the first fireproof sealing model is inferior to the second fireproof sealing model. The conclusions of the study are meaningful to improve the thermodynamic performance of the fireproof sealing in the converter station.