Thiacalix[4]arene-protected alkynyl Agn (n = 9, 18) nanoclusters: syntheses, structural characterizations, photocurrent responses and fluorescence properties

Xie, Wen-Xuan; Xue, Chun-Hui; Liu, Meng; Zhou, Kun; Gu, Hui-Hao; Ji, Jiu-Yu; Chen, Bao-Kuan; Liu, Na; Bi, Yan-Feng

doi:10.1039/d3dt02285d

Dalton Trans.

2023

DOI: 10.1039/d3dt02285d

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Thiacalix[4]arene-protected alkynyl Ag_n (n = 9, 18) nanoclusters: syntheses, structural characterizations, photocurrent responses and fluorescence properties

Wen-Xuan Xie,

Chun-Hui Xue,

Meng Liu

et al.

Abstract: Ag9 and Ag18 were obtained, characterized, and studied for photocurrent responses and fluorescence properties, providing a guide for controlled synthesis and studying the structure-activity relationship of calixarene-protected alkynyl Ag clusters.

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Advancements in Atomically Precise Nanocluster Protected by Thiacalix[4]arene

Gupta,

Wang,

Mohan

et al. 2024

Advanced Materials

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Coinage metal nanoclusters (NCs), comprising a few to several hundred atoms, are prized for their size‐dependent properties crucial in catalysis, sensing, and biomedicine. However, their practical application is often hindered by stability and reactivity challenges. Thiacalixarene, a macrocyclic ligand, shows promise in stabilizing silver, copper, and bimetallic NCs, enhancing their structural integrity and chemical stability. This investigation delves into the unique properties of thiacalix[4]arene and their role in bolstering NC stability, catalytic efficiency, and sensing capabilities. The current challenges and future prospects are critically evaluated, underscoring the transformative impact of thiacalix[4]arene in nanoscience. This review aims to broaden the utilization of atomically precise coinage metal NCs, unlocking new avenues across scientific and industrial applications.

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Advancements in Atomically Precise Nanocluster Protected by Thiacalix[4]arene

Gupta,

Wang,

Mohan

et al. 2024

Advanced Materials

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Thiacalix[4]arene macrocycles as versatile building blocks for the rational design of high-nuclearity metallic clusters, metallamacrocycles, porous coordination cages and containers

Khariushin,

Bulach,

Solovieva

et al. 2024

Coordination Chemistry Reviews

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Inorganic–organic hybrids based on Keggin-type polyoxometalate@Cu/Ag for degradation/absorption of methylene blue and electrocatalytic property

Chen,

Wang,

et al. 2025

Vacuum

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Thiacalix[4]arene-protected alkynyl Ag_n (n = 9, 18) nanoclusters: syntheses, structural characterizations, photocurrent responses and fluorescence properties

Abstract: Ag9 and Ag18 were obtained, characterized, and studied for photocurrent responses and fluorescence properties, providing a guide for controlled synthesis and studying the structure-activity relationship of calixarene-protected alkynyl Ag clusters.

Cited by 4 publications

References 80 publications

Advancements in Atomically Precise Nanocluster Protected by Thiacalix[4]arene

Advancements in Atomically Precise Nanocluster Protected by Thiacalix[4]arene

Thiacalix[4]arene macrocycles as versatile building blocks for the rational design of high-nuclearity metallic clusters, metallamacrocycles, porous coordination cages and containers

Inorganic–organic hybrids based on Keggin-type polyoxometalate@Cu/Ag for degradation/absorption of methylene blue and electrocatalytic property

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