Tungsten incorporated diamond like carbon nanocomposite¯lms were deposited onto Si substrate by using target biased ion beam assisted deposition. The e®ect of W target bias voltage on the chemical bonding, structure, surface morphology and mechanical properties of DLC¯lms were investigated by means of XPS, Raman spectroscopy, AFM and Nanoindentation. It was found that the content of W in the¯lms increased from 6 at.% to 13.7 at.% due to the increase in target bias voltage from À300 V to À700 V. XPS analysis revealed that most of the tungsten starts to react with carbon to form WC nanoparticles. Raman analysis shows that with the increase of W fraction in the DLC matrix, the intensity ratio I D /I G increases and the G band shifts to higher wavenumber. Thus it proves that the incorporation of tungsten leads to increase in sp 2 hybridized carbon content, and hence decrease in the hardness of W-DLC¯lms compared to that of the pure DLC¯lms. The result of AFM indicates that the surface roughness of the DLC gets modi¯ed with the incorporation of tungsten.