Abstract:In this chapter, we have discussed the history of the resurgence of thiol–ene/yne click chemistry in polymer science along with their mechanistic pathways under radical conditions either thermally or photochemically initiated. The recent instances of the utilization of the thiol–ene/yne click reaction for synthesis of polymeric networks, linear and hyperbranched polymers, and dendrimers are highlighted. Stereo-selective polymer synthesis via thiol–yne click polymerization is an important recent development tha… Show more
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