Third-order nonlinear optical properties of the phenothiazinium chlorides at 532nm

Lu, Yue-Ting; Ge, Jian‐Feng; Xu, Qingfeng; Yang, Yong; Li, Najun; Sun, Rong; Xia, Xinhui; Song, Yinglin; Lu, Jianmei

doi:10.1016/j.dyepig.2010.09.006

Cited by 10 publications

(4 citation statements)

References 35 publications

(27 reference statements)

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“…For metal-free phthalocyanines, the Q band is typically split into two main components while metal-containing phthalocyanines exhibit only a single Q band in their visible spectra. The exact position of these bands depends on the particular structure, metal complexation and peripheral substituents [33,34]. Metal incorporation induces a decrease in the extinction coefficient for the Q (and B) band.…”

Section: Uvevis Spectroscopymentioning

confidence: 99%

Optical and structural characterization of thin films containing metallophthalocyanine chlorides

Zawadzka¹,

Karakas²,

Płóciennik³

et al. 2015

Dyes and Pigments

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International audience

The structural and optical investigation of thin films containing aluminum and gallium phthalocyanine chlorides is presented. The films were fabricated by Physical Vapor Deposition technique onto quartz substrates and annealed after fabrication in an ambient atmosphere for 24 h at the temperature equal to 150 °C or 250 °C. The experimental results and theoretical calculation of the Third Harmonic Generation process are reported. The third order nonlinear optical properties are expected and can be more or less accurately predicted due to the assembly of the molecules and theoretical calculations of the frequency-dependent dipole polarizabilities, third hyperpolarizabilities, third order susceptibilities, frontier and second frontier molecular orbitals. These parameters were used to understand the relationship of optical properties with the molecular structures. We found that the annealing process causes formation of nanostructures and the value of the third order optical susceptibility makes these materials interesting for future nonlinear optical applications.

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Section: Uvevis Spectroscopymentioning

confidence: 99%

Optical and structural characterization of thin films containing metallophthalocyanine chlorides

Zawadzka¹,

Karakas²,

Płóciennik³

et al. 2015

Dyes and Pigments

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International audience

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“…By the following equations, the susceptibility χ (3) and hyperpolarizability γ can be obtained: 87,88 Re χ (3) (esu) = cn 0 n 2 (m 2 W −1 )/120π 2 Im χ (3) (esu) = c 2 n 0 2 β (m W −1 )/240π2 ω χ (3) (esu) = [( χ (3) I ) 2 + ( χ (3) R ) 2 ] 1/2 γ = χ (3) /[ N (( n 0 2 + 2)/3) 4 ]where ω is the angular frequency of the light field, N is the density of molecules in the unit of the number of molecules per cm 3 and n 0 is the linear refractive index of the acetonitrile ( n 0 = 1.344).…”

Section: Methodsmentioning

confidence: 99%

“…By the following equations, the susceptibility χ (3) and hyperpolarizability γ can be obtained: 87,88 Re χ ð3Þ ðesuÞ ¼ cn 0 n 2 ðm 2 W À1 Þ=120π 2…”

Section: Z-scan Measurementsmentioning

confidence: 99%

Macrocyclic Se₄N₂[7,7]ferrocenophane and Se₂N[10]ferrocenophane containing benzyl unit: synthesis, complexation, crystal structures, electrochemical and optical properties

Song

et al. 2016

Dalton Trans.

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Two novel macrocyclic polyselena[n]ferrocenophanes containing a pendent benzyl unit, 20-membered Se4N2[7,7]ferrocenophane (L1) and 10-membered Se2N[10]ferrocenophane (L2), were designed and synthesized. The reaction of L1 with two molar amounts of metal salts (M = Cu(+), Cu(2+), Pd(2+) and Hg(2+)) led to six dimetallic complexes 1-6. A crystallographic study revealed that each metal center in 1-5 was tetracoordinated to two selenium atoms from different ferrocene units, one aliphatic nitrogen atom and one co-ligand. The structures of the complexes contain a two-fold axis perpendicular to the molecular plane with two pendant benzyl moieties in an anti-conformation. Macrocycle L1 gives significant electrochemical, linear and third-order nonlinear optical responses to Cu(2+) and Hg(2+). The DFT/B3LYP calculations of 4 demonstrated a small HOMO-LUMO energy gap and delocalization of the π-electron cloud in the frontier molecular orbitals, which led to the enhancement of molecular NLO properties after complexation. The results show that the oxidation state of the ferrocene unit is accompanied by significant differences in the corresponding absorption spectra and third-order NLO properties.

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“…[27][28][29] In this effort, Schiff base compounds have seen gradual growth owing to their essential features, including synthetic ease, less or no sensitivity toward air and moisture, optical tunability, and strong metal binding ability. 30,31 Contextually, a diverse panel of Schiff base probes have been employed for uorescence-based detection of various analytes such as cations, [32][33][34][35] anions, 36 pesticides, 37,38 and antibiotics/drugs; [39][40][41][42] nevertheless, only a few demonstrate the use a Department of Chemistry, Applied Science Cluster, University of Petroleum and Energy Studies (UPES), Dehradun-248007, Uttarakhand, India. E-mail: sushil.k@ddn.upes.…”

Section: Introductionmentioning

confidence: 99%

Turn-on detection of Al³⁺ ions using quinoline-based tripodal probe: mechanistic investigation and live cell imaging applications

Goswami,

Naithani,

Goswami

et al. 2024

Anal. Methods

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Third-order nonlinear optical properties of the phenothiazinium chlorides at 532nm

Cited by 10 publications

References 35 publications

Optical and structural characterization of thin films containing metallophthalocyanine chlorides

Optical and structural characterization of thin films containing metallophthalocyanine chlorides

Macrocyclic Se₄N₂[7,7]ferrocenophane and Se₂N[10]ferrocenophane containing benzyl unit: synthesis, complexation, crystal structures, electrochemical and optical properties

Turn-on detection of Al³⁺ ions using quinoline-based tripodal probe: mechanistic investigation and live cell imaging applications

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Third-order nonlinear optical properties of the phenothiazinium chlorides at 532nm

Cited by 10 publications

References 35 publications

Optical and structural characterization of thin films containing metallophthalocyanine chlorides

Optical and structural characterization of thin films containing metallophthalocyanine chlorides

Macrocyclic Se4N2[7,7]ferrocenophane and Se2N[10]ferrocenophane containing benzyl unit: synthesis, complexation, crystal structures, electrochemical and optical properties

Turn-on detection of Al3+ ions using quinoline-based tripodal probe: mechanistic investigation and live cell imaging applications

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Resources

About

Macrocyclic Se₄N₂[7,7]ferrocenophane and Se₂N[10]ferrocenophane containing benzyl unit: synthesis, complexation, crystal structures, electrochemical and optical properties

Turn-on detection of Al³⁺ ions using quinoline-based tripodal probe: mechanistic investigation and live cell imaging applications