2001
DOI: 10.1016/s0379-6779(00)01036-5
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Third-order nonlinear optical properties of new square planar complexes with donor-metal-acceptor structure

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Cited by 3 publications
(2 citation statements)
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“…Despite the intense interest in the related [Pt(II)(diimine)(dithiolate)] complexes, only one prior study of a [Pt(II)(py) 2 (dithiolate)] complex, [Pt(4-CH 3 -py) 2 (mnt)], has previously been reported however in this case the electronic properties have not been thoroughly studied. 10 Pyridyl ligands have occasionally been used in Ruthenium DSSC sensitisers [11][12][13][14] but have not been widely investigated. They could offer flexible synthetic options and tunability of the absorption spectrum for a dye as well as possibly higher molar extinction coefficients than analogous bpy complexes.…”
Section: Introductionmentioning
confidence: 99%
“…Despite the intense interest in the related [Pt(II)(diimine)(dithiolate)] complexes, only one prior study of a [Pt(II)(py) 2 (dithiolate)] complex, [Pt(4-CH 3 -py) 2 (mnt)], has previously been reported however in this case the electronic properties have not been thoroughly studied. 10 Pyridyl ligands have occasionally been used in Ruthenium DSSC sensitisers [11][12][13][14] but have not been widely investigated. They could offer flexible synthetic options and tunability of the absorption spectrum for a dye as well as possibly higher molar extinction coefficients than analogous bpy complexes.…”
Section: Introductionmentioning
confidence: 99%
“…Η αρχή λειτουργίας της στηρίζεται στην παραγωγή εξιτονίων και τη διάστασή τους σε ζεύγη ηλεκτρονίων-οπών [115] Ο λόγος για τον οποίο αυτά τα υλικά αποτελούν κέντρο μελέτης αυτών των ιδιοτήτων είναι το γεγονός ότι τα υλικά αυτά εμφανίζουν έντονη ζώνη απορρόφησης κοντά στην περιοχή του εγγύς υπέρυθρου ενώ παράλληλα έχουν ισχυρή φωτοσταθερότητα [120]. Η μέθοδος η οποία χρησιμοποιείται κυρίως για τη μελέτη αυτών των ιδιοτήτων είναι η Z-scan [120][121]. Η επιλογή αυτής της τεχνικής για την μελέτη των μη γραμμικών οπτικών ιδιοτήτων αυτών των ενώσεων οφείλεται στην πειραματική απλότητά της καθώς και στη δυνατότητά της να προσδιορίζει τη μη γραμμική διάθλαση και απορρόφηση.…”
Section: φωτοανιχνευτέςunclassified