Aqueous
lubricants are gaining attention due to significant advantages
such as being environmentally friendly, tunable, and thermally stable.
The oil and gas industry can use such additives to utilize in water-based
fluids for applications where small sliding velocities and large lateral
forces require enhanced lubrication. This investigation aims to compare
the effects of two different additives: (i) inorganic fullerene-like
tungsten disulfide (IF-WS2) and (ii) an alkanolamine ionic
liquid denoted as AA-IL. Both additives were paired with three different
base fluids, deionized water (DIW), aqueous NaCl, and aqueous CaCl2, to measure the impact on fluids commonly utilized in the
field. The addition of IF-WS2 to all three solutions resulted
in a 30–60% decrease in the coefficient of friction (COF) and
wear. Surface analysis by X-ray photoelectron spectroscopy (XPS) and
energy-dispersive X-ray spectroscopy (EDS) showed that the formation
of a tribofilm (tungsten oxide layer) is primarily responsible for
tribological improvements. The AA-IL did not show evidence of any
chemical interaction. Instead, a physically bonded film of the AA-IL
on the steel surface enabled the improved COF (40–50% reduction)
and wear response. Both additives are effective in very small amounts
and provide excellent wear and friction reduction properties.