Synchrotron Radiation Computed Tomography (SRCT) and Synchrotron Radiation ComputedLaminography (SRCL) permit 3D non--destructive evaluation of fracture micro--mechanisms at high spatial resolutions. Two types of particle--toughened Carbon Fibre Reinforced Polymer (CFRP) composites were loaded to allow crack growth in Modes I and II to be isolated and observed in standard and non--standard specimen geometries. Both materials failed in complex and distinct failure modes, showing that interlaminar fracture in these materials involves a process zone rather than a singular crack tip. The work indicates that incorporating particle/resin, fibre/interlayer and neat resin failure is essential within models for material response, since the competition between these mechanisms to provide the energetically favourable crack path influences the macro--scale toughness. The work uniquely combines the strengths of SRCT and SRCL to compare failure micro--mechanisms between two specimen geometries, whilst assessing any edge effects and providing powerful insight into the complex micro--mechanical behaviour of these materials.