Three-dimensional carbon frameworks enabling MoS2 as anode for dual ion batteries with superior sodium storage properties

Cui, Chunyu; Wei, Zengxi; Xu, Jiantie; Zhang, Yiqiong; Liu, Shenghong; Liu, Huan; Mao, Minglei; Wang, Shuangyin; Ma, Jianmin; Dou, Shi Xue

doi:10.1016/j.ensm.2018.03.011

Cited by 131 publications

(74 citation statements)

References 63 publications

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“…To further improve the cycling stability of MoS 2 based DIB, Cui et al . developed a MoS 2 anode supported by 3D carbon fibers and coated with a carbon layer.…”

Section: Strategies To Improve Reaction Kinetics Of Cationsmentioning

confidence: 99%

Strategies towards Low‐Cost Dual‐Ion Batteries with High Performance

et al. 2019

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Rocking‐chair based lithium‐ion batteries (LIBs) have extensively applied to consumer electronics and electric vehicles (EVs) for solving the present worldwide issues of fossil fuel exhaustion and environmental pollution. However, due to the growing unprecedented demand of LIBs for commercialization in EVs and grid‐scale energy storage stations, and a shortage of lithium and cobalt, the increasing cost gives impetus to exploit low‐cost rechargeable battery systems. Dual‐ion batteries (DIBs), in which both cations and anions are involved in the electrochemical redox reaction, are one of the most promising candidates to meet the low‐cost requirements of commercial applications, because of their high working voltage, excellent safety, and environmental friendliness compared to conventional rocking‐chair based LIBs. However, DIB technologies are only at the stage of fundamental research and considerable effort is required to improve the energy density and cycle life further. We review the development history and current situation, and discuss the reaction kinetics involved in DIBs, including various anionic intercalation mechanism of cathodes, and the reactions at the anodes including intercalation and alloying to explore promising strategies towards low‐cost DIBs with high performance.

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“…To further improve the cycling stability of MoS 2 based DIB, Cui et al . developed a MoS 2 anode supported by 3D carbon fibers and coated with a carbon layer.…”

Section: Strategies To Improve Reaction Kinetics Of Cationsmentioning

confidence: 99%

Strategies towards Low‐Cost Dual‐Ion Batteries with High Performance

et al. 2019

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“…Sodium-ion batteries (SIBs), as an alternative energy storage system for lithium-ion batteries (LIBs), have attracted increasing attention due to their low cost and the abundant resource of sodium (Gao et al, 2017; Cui et al, 2018; Liang et al, 2018c). The electrochemical performance of SIBs is closely related to the properties of electrode materials, especially anode materials (Chen et al, 2018; Fan et al, 2018; Hu A. J. et al, 2018; Liang et al, 2018b,d; Wan et al, 2018; Wei et al, 2018).…”

Section: Introductionmentioning

confidence: 99%

Porous NaTi2(PO4)3 Nanocubes Anchored on Porous Carbon Nanosheets for High Performance Sodium-Ion Batteries

et al. 2018

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NaTi2(PO4)3 has attracted great interest as anode material for sodium ion batteries owing to its open three-dimensional framework structure and limited volume changes during the charge and discharge process. However, the poor intrinsic electronic conductivity of NaTi2(PO4)3 needs to be improved for high rate capability. In this work, porous NaTi2(PO4)3 nanocubes anchored on porous carbon nanosheets (NaTi2(PO4)3/C) are designed and developed. This material exhibits a large discharge capacity and good rate capacity including a first discharge capacity of 485 mAh g−1 at a current density of 0.1 A g−1, and 98 mAh g−1 retained at a high rate of 4 A g−1 even after 2,000 cycles. These results suggest that NaTi2(PO4)3/C is a promising anode material for sodium-ion batteries.

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“…To accelerate the ion diffusion kinetics in the cathode in SIBs, an unexpected way is introducing graphitic carbon with redox amphotericity as cathode material, which has been demonstrated that anion intercalation/deintercalation into/from graphite layer shows intrinsic fast diffusion behavior in dual‐ion batteries . On the other hand, to improve the Na + diffusion kinetics in the anode, other than using conventional battery‐type materials, a simple and efficient way is employing capacitive‐type material, which not only exhibits fast kinetics but also shows excellent structural stability.…”

Section: Figurementioning

confidence: 99%

Sodium‐Ion Hybrid Battery Combining an Anion‐Intercalation Cathode with an Adsorption‐Type Anode for Enhanced Rate and Cycling Performance

Lang

Zhang

et al. 2019

Batteries & Supercaps

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Sodium‐ion batteries (SIBs) are based on natural abundant and low‐cost materials and show a good chemical safety. They have thus become an alternative battery technology to conventional lithium‐ion batteries. However, SIBs usually suffer from poor rate capability and insufficient cycling performance caused by the sluggish reaction kinetics of the large Na+ ions, restricting their practical application. Herein, we report a novel sodium‐ion hybrid battery (SHB) combining an anion intercalation‐type graphite cathode material with an adsorption‐type hierarchical porous carbon anode material. The hierarchical porous amorphous carbon is derived from a natural biomass template with macro‐, meso‐, and micro‐ pores as well as high specific surface area, which are beneficial for fast adsorption/desorption of Na+ ions. Consequently, attributed from the hybrid battery design, this SHB exhibits excellent rate capability and cycling performance with a reversible capacity of 80 mAh g−1 at 2 C over a voltage window of 0–3.8 V and capacity retention of 87 % after 1000 cycles at 10 C.

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Three-dimensional carbon frameworks enabling MoS2 as anode for dual ion batteries with superior sodium storage properties

Cited by 131 publications

References 63 publications

Strategies towards Low‐Cost Dual‐Ion Batteries with High Performance

Strategies towards Low‐Cost Dual‐Ion Batteries with High Performance

Porous NaTi2(PO4)3 Nanocubes Anchored on Porous Carbon Nanosheets for High Performance Sodium-Ion Batteries

Sodium‐Ion Hybrid Battery Combining an Anion‐Intercalation Cathode with an Adsorption‐Type Anode for Enhanced Rate and Cycling Performance

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