In this letter, an annular anode is designed for producing arc plasmas with a large non-equilibrium region by using a counterflow cold gas through the annular anode. The coupled mass-momentum-energy exchange processes in an argon arc plasma are studied numerically and experimentally. The counter-injection of the cold argon gas from the center of the anode leads to a steep gradient of the heavy-particle temperature due to the formation of a thin stagnation layer resulting from the interaction of the high temperature plasma with the cold gas; and in particular, a large volume non-equilibrium “dark” plasma region is obtained above the anode surface. The results show that, with the enhancement of the convective heat transfer process in the plasma core region, the fraction of the non-equilibrium region to the whole arc plasma region reaches 92.2% where the heavy-particle temperature can be reduced significantly, e.g., ~ 2300 K, while simultaneously, the electron temperature and number density are remained at high levels greater than 8000 K and 2.4×1020 m-3, respectively, under the operating condition studied in this letter. This research not only deepens the understanding to the non-equilibrium synergistic transport mechanisms of arc plasmas, but also provides a method for producing a large volume non-equilibrium plasma region so as to promote various existing applications, or even creating new applications in the future.