Three new Ag(I) thiosaccharinate complexes: Synthesis, structural studies, spectral characterization and theoretical analysis

Zn thiosacharinates: From ionic to polymeric structures. Synthesis, characterization and cell proliferation inhibition studies

“…The distances obtained are a good reproduction of the experimentally observed structural parameters. The observed differences are in the range of those previously reported for other silver thiosaccharinates [9]. The differences among calculated and experimental angles are due to the packing in the solid state.…”

“…The initial geometry optimization of complex 1 was performed with the semi empirical PM3 method. The geometry thus obtained was used as starting point for the density functional theory (DFT) [14] calculations, that were performed with the B3LYP functional [15], which is known to be an appropriate methodology for the study on metal thiosacharinates complexes with nitrogen donor co-ligands [9]. Zero point energy was computed at the 6-31+G* level for C, H, S, N and O atoms and employing the LANL2DZ effective core potential basis set for Zn.…”

“…As other heterocyclic chalcogenones, thiosaccharine (the thione form of saccharin, C 6 H 4 S(O) 2 NHC(S), 1,1-dioxo-1,2-benzisothiazole-3-thione) can bind a metal ion in its anionic form either as monodentate species either via the thionate sulphur atom or the thioamido nitrogen atom, or as an ambidentate ligand via a variety of bonding modes. The coordination chemistry of thiosaccharine with several transition metals (Cd, Tl, Pd, Pt, Ag, Au, Cu, Bi) has been previously investigated and reported in detail [7,8,9 and references therein]. So far, the versatility of this anion has been extensively demonstrated in the different complexes described.…”

A comparative study of the coordination of saccharinate, thiosaccharinate and benzisothiozolinate ligands to cyclometalated [Pd(Me2NCH2C6H4-κN,C)(μ-Cl)]2: Molecular structures of [Pd(Me2NCH2C6H4-κN,C)(µ-X)]2 (X = sac, bit and tsac) and [Pd(Me2NCH2C6H4-κN,C)Cl(ampyH-κN)] (ampyH = 2-amino-3-methylpyridine)

“…The coordination chemistry of thiosaccharinate has also received recent attention [2][3][4][5][6][7][8][9][10][11][12][13][14][15][16][17][18], but that of benzisothiozolinate (bit) remains virtually unexplored [19][20]…”

Structure and electrical properties of a one-dimensional polymeric silver thiosaccharinate complex with argentophilic interactions

“…The synthesis of coordination compounds with Ag I metal centres results in a large panoply of different structural motifs, even when using similar starting coligands, due to the extreme coordination versatility of the Ag I cation. In the case of silver thiosaccharinates, this characteristic has been widely tested (Burrow et al, 2016).…”