Three novel d<sup>7</sup>/d<sup>10</sup> metal complexes with N-heterocyclic ligand of 2,6-bis(3-pyrazolyl)pyridine: synthesis, structure, surface photovoltage spectroscopy and photocatalytic activity

Hou, Ya Nan; Wang, Zhi Nan; Guan, Qing Lin; Wang, Xuan; Zhang, Rui; Xing, Yong Heng

doi:10.1039/c4ra02015d

Cited by 10 publications

(1 citation statement)

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“…In recent years, uranyl complexes have attracted much attention for exploring reactivity and coordination behavior of 5f -elements, developing suitable trivalent actinide (An(III)) extractants for nuclear remediation [1], screening highly effective chelators structure for decorporation of trivalent actinide (An(III)) [2], and investigating applications in the fields of catalysis, ion exchange, sensors, and photochemistry [3][4][5].…”

Section: Introductionmentioning

confidence: 99%

Investigation on the Synthesis and Photocatalytic Property of Uranyl Complexes of the β-Diketonates Biscatecholamide Ligand

Zhang

Jin

Peng

et al. 2017

International Journal of Photoenergy

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A series of uranyl complexes have been synthesized by reacting hexadentate ligands CH 2 [COO (CH 2 ) n CAM; = 2, 3, 4] 2 [CAM = 2,3-Ph(OH) 2 CONH] containing the catecholamide (CAM) group and -diketonates framework with uranyl nitrate. They were characterized by FTIR, UV-vis, 1 H NMR, XPS, TGA, and elemental analysis. The analysis revealed that oxygen atom of -diketonate did not bind to uranyl ion in complexes 1-3. The photocatalytic degradation properties of the target complexes for degradation of rhodamine B (RhB) were investigated. The result indicated that approximately 74%, 71%, and 67% RhB were degraded in the presence of complexes 1-3 after about 210 min, respectively. Consequently, complexes 1-3 have excellent photocatalytic degradation property.

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Section: Introductionmentioning

confidence: 99%

Investigation on the Synthesis and Photocatalytic Property of Uranyl Complexes of the β-Diketonates Biscatecholamide Ligand

Zhang

Jin

Peng

et al. 2017

International Journal of Photoenergy

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Photocatalytic Decontamination of Wastewater Containing Organic Dyes by Metal–Organic Frameworks and their Derivatives

et al. 2016

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Photoactive metal–organic frameworks (MOFs) have lately emerged as a class of crystalline porous materials, which provides an advanced platform to develop catalysts for the photocatalytic decolorization of wastewater. Controllable integration of pure MOFs into other active materials creates fabrication protocols for new multifunctional hybrids with superior photocatalytic properties for dye degradation into individual components, and the calcination of transition‐metal MOF precursors affords a convenient and practical route for preparation of nanosized photocatalysts with novel structures and good purity. Although the application of pure MOFs for organic pollutant decomposition has been reviewed previously, there have been significant advances in diverse MOF‐based composites and their derivatives for dye degradation, which have rarely been reviewed. This review aims to fill this gap and discuss the various influencing factors, the reaction kinetics, and mechanisms of dye degradation, considering the period from 2014 to 2016. Finally, the challenges and outlooks for dye decomposition by MOF‐based materials are suggested.

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Seven new complexes based on various coordination modes of bifunctional ligand: Luminescent sensing and magnetic properties

Zhang

Yan

Zhang

et al. 2019

Inorganica Chimica Acta

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Three novel d⁷/d¹⁰ metal complexes with N-heterocyclic ligand of 2,6-bis(3-pyrazolyl)pyridine: synthesis, structure, surface photovoltage spectroscopy and photocatalytic activity

Abstract: We synthesized three novel d7/d10 metal complexes with 2,6-bis(3-pyrazolyl)pyridine and studied their surface photovoltage spectra and photocatalytic activities.

Cited by 10 publications

References 57 publications

Investigation on the Synthesis and Photocatalytic Property of Uranyl Complexes of the β-Diketonates Biscatecholamide Ligand

Investigation on the Synthesis and Photocatalytic Property of Uranyl Complexes of the β-Diketonates Biscatecholamide Ligand

Photocatalytic Decontamination of Wastewater Containing Organic Dyes by Metal–Organic Frameworks and their Derivatives

Seven new complexes based on various coordination modes of bifunctional ligand: Luminescent sensing and magnetic properties

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Three novel d7/d10 metal complexes with N-heterocyclic ligand of 2,6-bis(3-pyrazolyl)pyridine: synthesis, structure, surface photovoltage spectroscopy and photocatalytic activity

Abstract: We synthesized three novel d7/d10 metal complexes with 2,6-bis(3-pyrazolyl)pyridine and studied their surface photovoltage spectra and photocatalytic activities.

Cited by 10 publications

References 57 publications

Investigation on the Synthesis and Photocatalytic Property of Uranyl Complexes of the β-Diketonates Biscatecholamide Ligand

Investigation on the Synthesis and Photocatalytic Property of Uranyl Complexes of the β-Diketonates Biscatecholamide Ligand

Photocatalytic Decontamination of Wastewater Containing Organic Dyes by Metal–Organic Frameworks and their Derivatives

Seven new complexes based on various coordination modes of bifunctional ligand: Luminescent sensing and magnetic properties

Contact Info

Product

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About

Three novel d⁷/d¹⁰ metal complexes with N-heterocyclic ligand of 2,6-bis(3-pyrazolyl)pyridine: synthesis, structure, surface photovoltage spectroscopy and photocatalytic activity