Mobility-control methods have the potential to improve coupled enhanced oil recovery (EOR) and carbon dioxide (CO 2 ) storage technique (CO 2 -EOR). There is a need for improved three-phase relative permeability models with hysteresis, especially including the effects of cycle dependency so that more-accurate predictions of these methods can be made. We propose new three-phase relative permeability and three-phase hysteresis models applicable to different fluid configurations in a porous medium under different wettability conditions. The relative permeability model includes both the saturation history and compositional effects. Three-phase parameters are estimated on the basis of saturation-weighted interpolation of two-phase parameters. The hysteresis model is an extension of the Land trapping model (Land 1968) but with a dynamic Land coefficient introduced. The trapping model estimates a constantly increasing trapped saturation for intermediatewetting and nonwetting phases. The hysteresis model overcomes some of the limitations of existing three-phase hysteresis models for nonwater-wet rocks and mitigates the complexity associated with commonly applied models in numerical simulators. The relative permeability model is validated by use of multicyclic threephase water-alternating-gas experimental data for nonwater-wet rocks. Numerical simulations of a carbonate reservoir with and without hysteresis were used to assess the effect of the saturation direction and saturation path on gas entrapment and oil recovery.
Background and Literature ReviewThe fluid configuration and flow in porous media delineate regions in saturation space where commonly used three-phase relative permeability models fail to replicate the physical behavior. There are empirical correlations routinely used on the basis of an assumed fluid configuration and pore occupancy that are difficult to generalize to other fluid configurations. The pore-filling sequences and, consequently, the phase dependency of the three-phase isoperms-i.e., contours of constant phase relative permeability in the saturation space-are partly characterized by the pore-size distribution, the spreading preference of the liquids on the pore-solid surfaces, and the spreading preferences of one fluid between the other fluids.Wettability state and interfacial tension (IFT) play crucial roles in the spreading behavior in porous media. Three-phase displacement processes and pore-scale mechanisms in physical etched micromodels revealed that fluid configurations can be categorized depending on the phase-spreading coefficient (C s ), defined as a balance of IFT (Adamson 1960;Øren and Pinczewski 1995):