Dark energy's thermodynamics is here revised giving particular attention to the role played by specific heats and entropy in a flat Friedmann-Robertson-Walker universe. Under the hypothesis of adiabatic heat exchanges, we rewrite the specific heats through cosmographic, model-independent quantities and we trace their evolutions in terms of z. We demonstrate that dark energy may be modeled as perfect gas, only as the Mayer relation is preserved. In particular, we find that the Mayer relation holds if j − q > 1 2 . The former result turns out to be general so that, even at the transition time, the jerk parameter j cannot violate the condition: j tr > 1 2 . This outcome rules out those models which predict opposite cases, whereas it turns out to be compatible with the concordance paradigm. We thus compare our bounds with the ΛCDM model, highlighting that a constant dark energy term seems to be compatible with the so-obtained specific heat thermodynamics, after a precise redshift domain. In our treatment, we show the degeneracy between unified dark energy models with zero sound speed and the concordance paradigm. Under this scheme, we suggest that the cosmological constant may be viewed as an effective approach to dark energy either at small or high redshift domains. Last but not least, we discuss how to reconstruct dark energy's entropy from specific heats and we finally compute both entropy and specific heats into the luminosity distance d L , in order to fix constraints over them through cosmic data.