Three water-soluble copper(ii) N-heterocyclic carbene complexes: toward copper-catalyzed ketone reduction under sustainable conditions
Mitu Sharma,
Amanda M. Perkins,
Raymond Femi Awoyemi
et al.
Abstract:A series of tridentate copper(ii) N-heterocyclic carbene (NHC) complexes with imidazole, benzimidazole, and 5,6-dimethylbenzimidazole azole rings were synthesized and comprehensively characterized via X-ray crystallography, ESI-MS, CV, and UV-Vis and EPR spectroscopic studies.
N-methylation of amines is of great interest in the synthesis of pharmaceuticals and valuable compounds, and the possibility to perform this reaction with an inexpensive and non-toxic substrate like CO2...
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